Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

Wyszukujesz frazę "CALPHAD" wg kryterium: Temat


Tytuł:
Modelowanie początkowego etapu wzrostu austenitu z przechłodzonej cieczy w układzie Fe-C-Si metodą pola fazowego
Modelling of Initial Stage of Austenite Growth in Fe-C-Si System Using Phase-Field Method
Autorzy:
Wróbel, M.
Burbelko, A.
Gurgul, D.
Tematy:
modelowanie krystalizacji
pole fazowe
metoda CALPHAD
solidification modelling
phase field
CALPHAD method
Pokaż więcej
Data publikacji:
2015
Powiązania:
https://bibliotekanauki.pl/articles/381432.pdf  Link otwiera się w nowym oknie
Źródło:
Archives of Foundry Engineering; 2015, 15, 4 spec.; 159-162
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Opis:
W pracy przeanalizowane zostały zmiany stężenia węgla i krzemu w fazie ciekłej i fazie γ stopu potrójnego Fe – 3,0% mas. C – 1,5% mas. Si podczas początkowego etapu wzrostu austenitu z przechłodzonej cieczy. Zmiany zachodzące na froncie krystalizacji analizowano poprzez wykorzystanie metody pola fazowego. Parametr pola fazowego ϕ jest związany ze składem fazowym: ϕ = 1 dla cieczy, ϕ = 0 dla roztworu stałego. Pole fazowe w tym przypadku nie jest zmienną konserwatywną, a dla opisu jej zmian zastosowano równanie Allen'a-Cahn'a. Za warunek początkowy symulacji przyjęto istnienie nierównowagowego zarodka fazy stałej o składzie chemicznym identycznym ze składem chemicznym przechłodzonej cieczy. W obliczeniach wykorzystano potencjały chemiczne pierwiastków w fazach. Różnica tych potencjałów stanowiła termodynamiczną siłę pędną przemiany, wywołującą przepływ pierwiastków. Wykazało to, że ścieżki zmian stężenia węgla i krzemu w fazie stałej oraz w cieczy są w znaczącym stopniu odchylone od równowagowej konody dla układu potrójnego o przyjętym składzie chemicznym. Oznacza to, że przyjęcie równowagowych współczynników rozdziału do wyznaczania zawartości pierwiastków stopowych w początkowym etapie wzrostu zarodka jest daleko idącym uproszczeniem. Przedstawiona metoda symulacji uwzględnia również wzajemny wpływ pierwiastków w obu fazach, w szczególności w austenicie, gdzie stężenie węgla na poziomie znacznie wyższym od wartości równowagowej w istotnym stopniu powoduje obniżenie zawartości krzemu.
In the paper changes of carbon and silicon concentration in liquid phase (L) and solid phase (γ) have been analysed for a triple alloy Fe-C-Si with the composition C – 3.0wt% and Si – 1.5wt%. The analysis was conducted at the initial stage of an austenite growth in the undercooled liquid. The changes occurring at the solidification front were analysed using the Phase Field method (PF). The phase field parameter ϕ is connected with the phase composition of the cell: ϕ = 1 for the liquid, ϕ = 0 for the solid phase. The phase field, in this case, is a non-conserved variable and for its description the Allen-Cahn equation was used. As an initial condition of the simulation it was assumed that the austenite nucleus had the same composition as the undercooled liquid. In the calculation chemical potential for each element in each phase was used. The difference in the chemical potential between phases was treated as the thermodynamic driving force of transformation causing the diffusion of the elements. This showed that the paths of carbon and silicon concentration changes in the solid and liquid are substantially deviated from the tie line for the triple alloy with fixed concentration. This means that the adoption of the equilibrium distribution coefficients at the initial stage of the nucleus growth is a big simplification. Presented method of the simulation takes also into account the mutual influence of the elements in both phases, in particular in the austenite where the carbon concentration is much higher than the equilibrium value causing reduction of the silicon concentration.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Diffusion Model of Binary Systems Controlled by Chemical Potential Gradient
Autorzy:
Wróbel, Marek
Burbelko, Andriy
Tematy:
diffusion
modelling
CALPHAD
chemical potential
Pokaż więcej
Data publikacji:
2022
Powiązania:
https://bibliotekanauki.pl/articles/2105206.pdf  Link otwiera się w nowym oknie
Źródło:
Journal of Casting & Materials Engineering; 2022, 6, 2; 39--44
2543-9901
Pojawia się w:
Journal of Casting & Materials Engineering
Opis:
The paper presents a model of diffusion in a single phase with chemical potential gradient as the driving force of the process. Fick’s laws are strictly empirical and the assumption that the concentration gradients are the driving forces of diffusion is far from precise. Instead, the gradient of chemical potential μi of component i is the real driving force. The matter of governing equations of models that incorporate this approach will be raised and discussed in this article. One of more important features is the ability to acquire results where diffusion against the concentration gradient may occur. The presented model uses the Finite Difference Method (FDM) and employs the CALPHAD method to obtain chemical potentials. The calculations of chemical potential are carried out for instant conditions – temperature and composition – in the entire task domain by Thermo-Calc via a TQ-Interface. Then the heterogeneity of chemical potentials is translated into mass transfer for each individual element. Calculations of two modelling tasks for one-dimension diffusion field were carried out. First: isothermal conditions with linear initial composition distribution and second: constant temperature gradient with uniform chemical composition in the specimen. Results for two binary solid solutions: Fe-C and Fe-Si, in the FCC phase for the given tasks will be presented. Modelling allows us to estimate the time needed to reach a desired state in a particular equilibrium or quasi-equilibrium state. It also shows the path of the composition change during the process. This can be used to determine whether the system at some point is getting close to the formation of another phase due to significant deviation from its initial conditions.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modelling the composition of carbides in nickel-based superalloys of directional crystallization
Autorzy:
Glotka, O. A.
Tematy:
nickel-based superalloys
directional solidification
alloying system
CALPHAD method
structure
composition of carbides
nadstopy niklu
krzepnięcie kierunkowe
metoda CALPHAD
struktura
węgliki
Pokaż więcej
Data publikacji:
2020
Powiązania:
https://bibliotekanauki.pl/articles/1818827.pdf  Link otwiera się w nowym oknie
Źródło:
Journal of Achievements in Materials and Manufacturing Engineering; 2020, 102, 1; 5--15
1734-8412
Pojawia się w:
Journal of Achievements in Materials and Manufacturing Engineering
Opis:
Purpose: The specifics of the influence of alloying elements on the chemical composition of various types of carbides, their topology and morphology for a multicomponent system of the type Ni-5Cr-9Co-6Al-1Ti-11.7W-1.1Mo-1.6Nb-0.15C using the calculation method CALPHAD. It is shown that the obtained dependences closely correlate with thermodynamic processes occurring in the system. Design/methodology/approach: This work presents the results of studies of the distribution of chemical elements in the composition of carbides, depending on their content in the system. Findings: It was found that the influence of alloying elements on the composition of carbides is complex and is described by complex. Research limitations/implications: An essential problem is the prediction of the structure and properties of heat-resistant alloys without or with a minimum number of experiments. Practical implications: The obtained dependences can be used both for designing new heat-resistant alloys and for improving the compositions of industrial alloys. Originality/value: The value of this work is that the obtained dependences of the influence of alloying elements on the dissolution (precipitation) temperatures and the distribution of elements in carbides in the alloy of the Ni-5Cr-9Co-6Al-1Ti-11.7W-1.1Mo-1.6Nb-0.15C.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic Assessment of Mushy Zone in Directional Solidification
Autorzy:
Mikołajczak, P.
Ratke, L.
Tematy:
aluminum alloy
directional solidification
mushy zone
CALPHAD technique
Fe intermetallics
β-Al5FeSi
stop aluminium
krzepnięcie kierunkowe
strefa półciekła
technika CALPHAD
Pokaż więcej
Data publikacji:
2015
Powiązania:
https://bibliotekanauki.pl/articles/380005.pdf  Link otwiera się w nowym oknie
Źródło:
Archives of Foundry Engineering; 2015, 15, 4; 101-109
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Opis:
Solidification of AlSiFe alloys was studied using a directional solidification facility and the CALPHAD technique was applied to calculate phase diagrams and to predict occurring phases. The specimens solidified by electromagnetic stirring showed segregation across, and the measured chemical compositions were transferred into phase diagrams. The ternary phase diagrams presented different solidification paths caused by segregation in each selected specimen. The property diagrams showed modification in the sequence and precipitation temperature of the phases. It is proposed in the study to use thermodynamic calculations with Thermo-Calc which enables us to visualize the mushy zone in directional solidification. 2D maps based on property diagrams show a mushy zone with a liquid channel in the AlSi7Fe1.0 specimen center, where significant mass fraction (33%) of β-Al5FeSi phases may precipitate before α-Al dendrites form. Otherwise liquid channel occurred almost empty of β in AlSi7Fe0.5 specimen and completely without β in AlSi9Fe0.2. The property diagrams revealed also possible formation of α–Al8Fe2Si phases.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic approach to the development and selection of hardfacing materials in energy industry
Autorzy:
Shihab, Thaer
Prysyazhnyuk, Pavlo
Semyanyk, Iryna
Anrusyshyn, Roman
Ivanov, Olexandr
Troshchuk, Lyubomyr
Tematy:
flux-cored electrodes
hardfacing
alloying system
Calphad method
wear resistance
Pokaż więcej
Data publikacji:
2020
Powiązania:
https://bibliotekanauki.pl/articles/409820.pdf  Link otwiera się w nowym oknie
Źródło:
Management Systems in Production Engineering; 2020, 2 (28); 84-89
2299-0461
Pojawia się w:
Management Systems in Production Engineering
Opis:
The overall study objection is selection and optimization all available thermodynamic data required for using calculation of phase diagram (CALPHAD) technique within the Fe-C-Cr-Mn-Si-Ti system. Such data collected in the thermodynamic database can be used for predicting the phase constitution states of a given composition for Fe-based hardfacing materials, which often use in energy industry in order to increase the abrasion and impact wear resistance of equipment parts. In order to compare theroretical calculation results with experimental data, four different types of hardfacing were deposited using flux-cored arc welding. Microstructure and chemical composition of deposited layers was investigated using optical and scanning electron microscopy together with energy dispersive X-ray spectroscopy. Comparison of experimental and computed results shows that they are in good agreement in meaning of presence of all-important phase equilibrium regions. The developed database can be used for rational selection of hardfacing materials for energy industry equipment and reasonable choice of new alloying systems.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Optimization of a Numerical Steel Foundry Simulation Through a Characterization of the Thermal Properties of the Materials
Autorzy:
Souêtre, Morgan
Vaucheret, Alexis
Jacquet, Philippe
Carton, Jean-François
Tematy:
foundry simulation
low-alloyed steel
green sand
thermal analysis
CALPHAD
Pokaż więcej
Data publikacji:
2022
Powiązania:
https://bibliotekanauki.pl/articles/2172386.pdf  Link otwiera się w nowym oknie
Źródło:
Journal of Casting & Materials Engineering; 2022, 6, 4; 76--80
2543-9901
Pojawia się w:
Journal of Casting & Materials Engineering
Opis:
In many foundries, numerical simulation is used to determine the origins of different defects as this tool allows the acceleration of the design process. However, the databases provided by different software do not seem to tally with the actual properties of the material. In fact, every foundry uses a different grade of steel and varying mixtures of sand. An evaluation of the impact of different material properties showed the importance of measuring every physical property to improve the database of the software. Following this, an experiment was conducted to evaluate the gap between numerical simulations and the results obtained through experimentation. This experiment, called thermal analysis, consists in measuring the solidification and cooling of a cylinder filled with liquid steel. After the calculation of the steel properties and a simulation with real experimental parameters, a comparison between each cooling curve was realized. This comparison shows that the calculated properties provide a simulated cooling curve which is closer to the experimental curve than the properties in the original database. We did not explore all of the metal properties in this study, but the modification of the sand properties was explored, together with the thermal conductivity of the steel and sand. These other measurements will be obtained in a future study.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reconstruction of the Late Bronze Age Foundry Process in Greater Poland: Analyzes and Simulations. Case Study of Hoard from Przybysław
Autorzy:
Garbacz-Klempka, Aldona
Piękoś, Marcin
Perek-Nowak, Małgorzata
Kozana, Janusz
Żak, Paweł
Fijołek, Andrzej
Silska, Patrycja
Stróżyk, Mateusz
Tematy:
archaeometallurgy
copper alloys
casting
CALPHAD
computer modeling
Late Bronze Age
Pokaż więcej
Data publikacji:
2022
Powiązania:
https://bibliotekanauki.pl/articles/2134106.pdf  Link otwiera się w nowym oknie
Źródło:
Archives of Metallurgy and Materials; 2022, 67, 3; 1125--1136
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Opis:
One of the most interesting categories of artifacts for archaeometallurgical research includes deposits of bronze items, so-called “metallurgists hoards”. They contain, aside of final products, many fragments of raw material and, moreover, metallurgical tools. An important source for the studies on the history of metallurgical technology is hoard from Przybysław, Greater Poland district. Thus, the aim of the work is the identification and interpretation of bronze-working practices and strategies adopted by prehistoric communities of the Late Bronze Age and the Early Iron Age (ca. 600 BC). The examined objects are characterized in terms of their design, structure, and chemical composition. The methods chosen for the studies of artifacts include: metallographic macro- and microscopic observations using optical microscopy (OM) and scanning electron microscopy (SEM), the analysis of chemical composition with the methods of energy dispersive X-ray spectroscopy (EDS), and X-ray fluorescence (ED-XRF). The thermodynamic analysis of the alloys was performed on the basis of the CALPHAD method. The experimental melts allowed to verify the theoretical considerations and to determine the characteristic temperatures of changes. The old casting technology can be analyzed basing on computer modeling and computer simulation methods. Simulations in the MAGMASOFT® software are a good example to illustrate how to fill a mould cavity with a molten bronze for a hoop ornament. It is also an appropriate tool to determine temperature distribution in a mould. The simulations also show the possible disadvantages with this old technology.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mathematical forecasting composition of secondary carbides in the single-crystal superalloys
Autorzy:
Glotka, O.A.
Olshanetskii, V.I.
Tematy:
single-crystal nickel-based superalloy
alloying system
CALPHAD method
structure
composition of secondary carbides
krystaliczny nadstop na bazie niklu
układ stopowy
metoda CALPHAD
struktura
skład węglików wtórnych
Pokaż więcej
Data publikacji:
2021
Powiązania:
https://bibliotekanauki.pl/articles/2175759.pdf  Link otwiera się w nowym oknie
Źródło:
Archives of Materials Science and Engineering; 2021, 111, 1; 34--41
1897-2764
Pojawia się w:
Archives of Materials Science and Engineering
Opis:
Purpose: Predicting the specifics of the distribution of alloying elements between secondary carbides, their topology, and morphology, as well as the composition for a single-crystal multicomponent system of the type Ni-11.5Cr-5Co-3.6Al-4.5Ti-7W-0.8Mo-0.06C using the calculated CALPHAD (passive experiment) versus scanning electron microscopy (active experiment). Design/methodology/approach: This work presents the results of studies of the distribution of chemical elements in the composition of carbides, depending on their content in the system. The studies were carried out using an electron microscope with computer analysis of images and chemical composition. Findings: It was found that the influence of alloying elements on the composition of carbides is complex and is described by complex dependencies that correlate well with the obtained experimental results. Research limitations/implications: An essential problem is the prediction of the structure and properties of superalloys without or with a minimum number of experiments. Practical implications: The obtained dependencies can be used both for designing new superalloys and for improving the compositions of industrial alloys. Originality/value: The value of this work is that the obtained dependences of the influence of alloying elements on the dissolution (precipitation) temperatures and the distribution of elements in secondary carbides in the superalloy of the Ni-11.5Cr-5Co-3.6Al-4.5Ti-7W- 0.8Mo-0.06C system. It was found that changes in the course of the curves of temperature dependence on the element content closely correlate with thermodynamic processes occurring in the system, that is, the curves exhibit extrema accompanying the change in the stoichiometry of carbides or the precipitation of new phases.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metoda CALPHAD – nowoczesna technika pozyskiwania danych termodynamicznych
Autorzy:
Wróbel, M.
Burbelko, A.
Tematy:
komputerowe wspomaganie produkcji odlewniczej
metoda CALPHAD
wykres fazowy Fe-C
temperatura zalewania
obróbka cieplna
computer aided foundry production
CALPHAD method
phase diagram of Fe-C
thermal treatment
Pokaż więcej
Data publikacji:
2014
Powiązania:
https://bibliotekanauki.pl/articles/380073.pdf  Link otwiera się w nowym oknie
Źródło:
Archives of Foundry Engineering; 2014, 14, 3 spec.; 79-84
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Opis:
Pierwsze spotkanie z metodą CALPHAD zazwyczaj zaczyna się od pytania co właściwie można za jej pomocą obliczyć? Niniejsza praca przytacza kilka przykładów w jaki sposób można pozyskać interesujące nas rezultaty obliczeń oraz jak je interpretować, a także definiuje obszar, w którym to podejście jest pomocne. Pokazano wzory obliczeń pomocnych przy wyznaczaniu parametrów procesów technologicznych, takich jak temperatury zalewania oraz obróbki cieplnej. Przedstawiono również sposób wyznaczenia wpływu pierwiastków stopowych na przesunięcie punktów w układzie żelazo-węgiel. Podano ideę obliczeń równowagowych oraz nierównowagowych aby pomóc w zdaniu sobie sprawy, że same wyniki są tylko jednym z elementów potrzebnych do zrozumienia rozważanego układu oraz, że wymagana jest odpowiednia znajomość materiału, nad którym się pracuje, aby dojść do wiarygodnych wniosków. Zostało także zaznaczone, że metoda CALPHAD, dzięki możliwości obliczeń układów wyższych rzędów z uwzględnieniem wielu faz, jest niezmiernie pomocna w tematach związanych z modelowaniem przemian fazowych.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of Values of Diffusion Coefficient on Results of Diffusion Modelling Driven by Chemical Potential Gradien
Autorzy:
Wróbel, Marek
Burbelko, Andriy
Tematy:
foundry industry
application of information technology
diffusion modelling
Calphad method
chemical potential
diffusion coefficient
przemysł odlewniczy
zastosowanie technologii informatycznej
modelowanie dyfuzyjne
metoda Calphad
potencjał chemiczny
współczynnik dyfuzji
Pokaż więcej
Data publikacji:
2022
Powiązania:
https://bibliotekanauki.pl/articles/2174626.pdf  Link otwiera się w nowym oknie
Źródło:
Archives of Foundry Engineering; 2022, 22, 3; 81--90
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Opis:
In the paper critical role of including the right material parameters, as input values for computer modelling, is stressed. The presented model of diffusion, based on chemical potential gradient, in order to perform calculations, requires a parameter called mobility, which can be calculated using the diffusion coefficient. When analysing the diffusion problem, it is a common practice to assume the diffusion coefficient to be a constant within the range of temperature and chemical composition considered. By doing so the calculations are considerably simplified at the cost of the accuracy of the results. In order to make a reasoned decision, whether this simplification is desirable for particular systems and conditions, its impact on the accuracy of calculations needs to be assessed. The paper presents such evaluation by comparing results of modelling with a constant value of diffusion coefficient to results where the dependency of Di on temperature, chemical composition or both are added. The results show how a given deviation of diffusivity is correlated with the change in the final results. Simulations were performed in a single dimension for the FCC phase in Fe-C, Fe-Si and Fe-Mn systems. Different initial compositions and temperature profiles were used.
Dostawca treści:
Biblioteka Nauki
Artykuł

Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies