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Wyświetlanie 1-10 z 61
Tytuł:
One-dimensional isothermal multicomponent diffusion-reaction model and its application to methanol synthesis over commercial Cu-based catalyst
Autorzy:
Lei, K.
Ma, H.
Zhang, H.
Ying, W.
Fang, D.
Tematy:
global kinetics
internal effectiveness factor
diffusion-reaction model
methanol synthesis
Pokaż więcej
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/778972.pdf  Link otwiera się w nowym oknie
Opis:
The present work was a study on global reaction rate of methanol synthesis. We measured experimentally the global reaction rate in the internal recycle gradientless reactor over catalyst SC309. The diffusion-reaction model of methanol synthesis was suggested. For model we chose the hydrogenation of CO and CO2 &enspas key reaction. CO and CO2 &enspwere key components in our model. The internal diffusion effectiveness factors of CO and CO2&enspin the catalyst were calculated by the numerical integration. A comparison with the experiment showed that all the absolute values of the relative error were less than 10%. The simulation results showed that decreasing reaction temperature and catalyst diameter were conducive to reduce the influence of the internal diffusion on the methanol synthesis.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Process simulation of dimethyl ether synthesis via methanol vapor phase dehydration
Autorzy:
Bai, Z.
Ma, H.
Zhang, H.
Ying, W.
Fang, D.
Tematy:
dimethyl ether
methanol dehydration to DME
process simulation
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Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/779378.pdf  Link otwiera się w nowym oknie
Opis:
The production processes included catalytic dehydration of methanol in an adiabatic fixed-bed reactor and two columns product separations. In this study, the technological process for dimethyl ether (DME) synthesis is built on PRO/II platform based on the combined parameters of the reaction dynamic model for methanol dehydration reaction, the improved NRTL model of the liquid phase, the PR model of vapor phase. In order to validate the proposed model, the simulation results have been compared with the available data from a set of industrial production equipment with a production capacity of 200 000 tonnes per annum. A comparison between the calculated and measured results has proved that these results are satisfactory. The bed height and the volume of the catalytic bed are calculated aim at one million t/a DME yields and while taking account of high-purity DME production. After discussing the influence of feed stage location and reflux ratio for DME product purity, the suitable unit operation conditions are chosen. Accordingly, accurate process simulation results provide the basis and guidance for an improvement and development of the similar industrial device.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of preparation method on the performance of PtSn/Al2O3 &enspcatalysts for acetic acid hydrogenation
Autorzy:
Zhang, K.
Zhang, H.
Ma, H.
Ying, W.
Fang, D.
Tematy:
Pt-Sn catalysts
preparation method
acetic acid hydrogenation
XPS
CO-FTIR
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Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/779525.pdf  Link otwiera się w nowym oknie
Opis:
PtSn/Al2O3 &enspcatalysts with a given loading of 1 wt% Pt and 1 wt% Sn were prepared by co-impregnation or successive impregnation with aqueous solutions of Pt, Sn precursors and a commercial alumina. The catalysts were characterized by N2 &enspadsorption, H2-TPR (H2&ensp temperature-programmed reduction), H2-pulse chemisorption, XPS (X-ray photoelectron spectroscopy) and CO-FTIR (Fourier transform infrared spectroscopy), and tested in the hydrogenation of acetic acid. The results showed that the preparation method affected both the chemical properties and their performance in the hydrogenation of acetic acid. Sn enrichment on the catalysts surface was observed on the co-impregnated catalyst and catalyst in which the Pt precursor had been loaded first. It was found that the modification of Pt was a function of the sequence of Sn addition as revealed by CO-FTIR. Co-impregnated catalyst showed the highest activity and ethanol selectivity.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of boron on ZSM-5 catalyst for methanol to propylene conversion
Autorzy:
Xu, A.
Ma, H.
Zhang, H.
Ying, W.
Fang, D.
Tematy:
methanol to propylene
ZSM-5
boron modifi cation
propylene
Pokaż więcej
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/777971.pdf  Link otwiera się w nowym oknie
Opis:
B-ZSM-5 catalysts were prepared by various modification methods with boric acid, including ion-exchange, impregnation and direct synthesis. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), NH3-Temperature Programmed Desorption (NH3-TPD), N2 adsorption-desorption, Fourier Transform Infrared spectrometry (FT-IR), 27Al and 11B MAS NMR spectra. The results revealed that the weak acidity of catalysts was significantly increased by modification. The catalytic activity was measured in a fixed bed at 460°C for methanol to propylene (MTP) reaction. The results of MTP reaction showed a great increment of the propylene selectivity for the boron modified samples, especially for the directly synthesized B-ZSM-5 which also displayed high activity and selectivity towards C2 =-C4 = olefins. It was found that the remarkable selectivity strongly depended on the intensity of weak acidity.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Książka = Book ; KS/2/1992/R33
Support systems for decision and negotiation processes * Volume 1 * The graph model for conflicts as a negotiation support tool
Autorzy:
Hipel, Keith
Fang, Liping
Kilgour, D.
Wydawca:
Instytut Badań Systemowych. Polska Akademia Nauk
Systems Research Institute. Polish Academy of Sciences
Powiązania:
Książka = Book
Opis:
245-259, [1] stron ; 21 cm
Bibliography p. 258-259
Bibliografia s. 258-259
245-259, [1] pages ; 21 cm
The graph model for conflicts is presented as a flexible approach for systematically studying real world disputes. Basic definitions underlying the graph model are reviewed and some representative solution concepts arc defined for describing possible human behaviour under conflict. To demonstrate the practical application of the graph model as a negotiation support tool, the modelling and analysis stages arc clearly illustrated using an international trading conflict, which arose over the export of Canadian softwood lumber to the United States. Besides showing representative modelling and analysis results, insights gained by carrying out a formal graph model study arc pointed out.
Dostawca treści:
RCIN - Repozytorium Cyfrowe Instytutów Naukowych
Książka
Tytuł:
Investigations of the Optical Band Positions and Spin-Hamiltonian Parameters for the Rhombic $VO^{2+}$ Complex in CsCl Crystal
Autorzy:
Fang, W.
Zheng, W.
Yang, D.
Tang, H.
Tematy:
71.70.Ch
75.10.Dg
61.72.Bb
76.30.Fc
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Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1365269.pdf  Link otwiera się w nowym oknie
Opis:
The optical band positions and spin-Hamiltonian parameters (g factors $g_{i}$ and hyperfine structure constants $A_{i}$, where i=x, y, z) of the rhombic $VO^{2+}$ complex in CsCl crystal are calculated together from two theoretical methods. One is the complete diagonalization (of energy matrix) method and another is the perturbation theory method. The calculated results from the two methods coincide and are in reasonable agreement with the experimental values. So, both methods are effective in the explanations of optical and electron paramagnetic resonance (EPR) data for $d^1$ ions in crystals. The calculations also suggest that in $d^1$ rhombic octahedra the ground state is almost a pure | $d_{xy}$ ⟩ state. This point is different from that of conjugate $d^9$ (e.g., $Cu^{2+}$) ions in rhombic octahedra where the ground state should be an admixture of ground and first excited states.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Generation of chirped microwave signal with any central frequency based on a nonuniformly spaced finite impulse response filter
Autorzy:
Chen, D.
Wang, R.
Pu, T.
Xiang, P.
Fang, T.
Zheng, J.
Xiong, J.
Tematy:
microwave photonics
microwave photonic filter
chirped microwave signal
dual drive Mach–Zehnder modulator
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Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Powiązania:
https://bibliotekanauki.pl/articles/174334.pdf  Link otwiera się w nowym oknie
Opis:
A novel optical approach to generating a chirped microwave signal by using a nonuniformly spaced finite impulse response filter is proposed and demonstrated. In this scheme, a narrowband Gaussian pulse is used as the original chirped-free signal, which is easy to be acquired. To eliminate the need of a wideband chirped-free signal, a mixer and a radio frequency signal are used to up-convert the spectrum of the original Gaussian signal. Therefore, the required frequency response can be calculated and reconstructed by a finite impulse response filter with nonuniformly spaced taps. Besides, a dual drive Mach–Zehnder modulator is used to realize single sideband modulation of the chirpedfree signal. Thus, the transfer function induced by the fiber dispersion is eliminated and the chirped microwave signal with any central frequency can be generated. In this paper, a design example of a filter with a central frequency of 10GHz is provided, and generation of the target chirped microwave signal is also demonstrated by numerical simulations.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heavy Metal Contamination of Surface Water and Groundwater in and Around Gejiu Tin Mine, Southwest China
Zanieczyszczenie wód powierzchniowych i podziemnych metalami ciężkimi w kopalni Gejiu Tin, południowo-zachodnie Chiny i jej okolicach
Autorzy:
Cheng, X.
Qi, W.
Danek, T.
Matysek, D.
Huang, Q.
Zhao, X.
Zhou, Z.
Fang, R.
Zou, L.
Xu, J.
Tematy:
metale ciężkie
zanieczyszczenie
kopalnia cyny Gejiu
wody powierzchniowe
wody kopalniane
heavy metals
contamination
Gejiu tin mine
surface water
mine water
Pokaż więcej
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Powiązania:
https://bibliotekanauki.pl/articles/317873.pdf  Link otwiera się w nowym oknie
Opis:
Heavy metal contamination due to mining activity is a global major concern because of its potential health risks to local inhabitants. The heavy metal contamination of surface water and ground water by mining activities in Gejiu tin-polymetallic mining area, Southwest China, was studied. Surface water and ground water were sampled and analyzed using AAS for Cr6+, Cd, As, Hg, Cu, Pb, Zn, Se, Fe and Mn. Analysis of HCO3–, Cl–, SO42–, F– and NO3– in water samples was also undertaken by ion chromatography. It was shown that none of water samples exceeded the guideline of Cr6+, Se and Hg, while the contamination degree of heavy metals was Mn > Fe > Cd > Zn > Pb > As > Cu, all of which were serious contamination except mild contamination for Cu. The ground waters were polluted much worse than surface water.
Zanieczyszczenie metalami ciężkimi spowodowane działalnością kopalń jest światowym problemem z powodu ryzyka utraty zdrowia przez okolicznych mieszkańców. Zbadano zanieczyszczenie wód powierzchniowych oraz wód podziemnych wywołane działalnością kopalni cyny w rejonie górniczym Gejiu, południowo-zachodnie Chiny. Pobrano próbki wody powierzchniowej oraz podziemnej i zanalizowano je ze względu na obecność Cd, As, Hg, Cu, Pb, Zn, Se, Fe oraz Mn. Analizy HCO3–, Cl–, SO42–, F– oraz NO3– w próbkach wody również zostały przeprowadzone za pomocą chromatografii jonowej. Ukazano, że żadna z badanych wód nie przekroczyła dopuszczalnych poziomów dla Cr6+, Se oraz Hg. Jednakże poziom zanieczyszczenia metali ciężkimi tj. Mn > Fe > Cd > Zn > Pb > As > Cu był wysoki, za wyjątkiem niewielkiego przekroczenia norm dla Cu. Wody podziemne były znacznie bardziej zanieczyszczone niż wody powierzchniowe.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, characterization and magnetic properties of metal pentafluoropropionates complexes with an alkyl nitronyl nitroxide biradical
Autorzy:
Fang, R. -B.
Yun, S.-P.
Zhao, Q.-H.
Liao, D.-Z.
Sun, B. -W.
Liu, Z. -L.
Jiang, Z.-H.
Współwytwórcy:
Polska Akademia Nauk. Komitet Nauk Chemicznych.
Polskie Towarzystwo Chemiczne.
Wydawca:
PWN
Powiązania:
Polish Journal of Chemistry
Opis:
s. 1797-1801
Dostawca treści:
RCIN - Repozytorium Cyfrowe Instytutów Naukowych
Książka
Wyświetlanie 1-10 z 61

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