- Tytuł:
- Magnetocaloric Effect in NiCl₂(bipy) at Low Temperatures
- Autorzy:
-
Ráczová, K.
Čižmár, E.
Feher, A. - Tematy:
-
75.30.Sg
75.30.Gw
75.10.Pq - Pokaż więcej
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Powiązania:
- https://bibliotekanauki.pl/articles/1032298.pdf  Link otwiera się w nowym oknie
- Opis:
- Magnetothermal properties of the compound NiCl₂(bipy), where bipy = 4,4'-bipyridine, were studied. The single-ion anisotropy of Ni(II) ions was estimated and its influence on magnetocaloric effect in NiCl₂(bipy) was investigated. Above the metamagnetic transition a maximum in the isothermal change of the magnetic entropy is reached near 11 K at field change from 0T to 7T with peak value -ΔS = 6J K¯¹ kg¯¹. The temperature dependence of ΔS above 7K agrees with the assumed easy-axis type of single-ion anisotropy. The inverse magnetocaloric effect, typical for ordered antiferromagnets, was observed in the ordered state of NiCl₂(bipy) only for isothermal magnetization in small fields up to 2T.
- Dostawca treści:
- Biblioteka Nauki
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