- Tytuł:
- XPS Study of "infinite Chain" Ca$\text{}_{2}$CuO$\text{}_{3}$ and Ca$\text{}_{0.5}$Sr$\text{}_{0.5}$CuO$\text{}_{2}$ Compounds
- Autorzy:
-
Jacyna-Onyszkiewicz, I.
Poltoracky, Yu. B. - Tematy:
-
79.60.-i
74.72.-h
74.72.Jt - Pokaż więcej
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Powiązania:
- https://bibliotekanauki.pl/articles/2013234.pdf Link otwiera się w nowym oknie
- Opis:
- Al K$\text{}_{α}$ excited photoelectron spectra (X-ray photoelectron spectroscopy) of the O 1s, Cu 2p, Ca 2p, Sr 3d core levels were measured for "infinite chain" Ca$\text{}_{2}$CuO$\text{}_{3}$ and Ca$\text{}_{0.5}$Sr$\text{}_{0.5}$CuO$\text{}_{2}$ compounds. The analysis indicates that for Ca$\text{}_{2}$CuO$\text{}_{3}$ the surface electronic structure is strongly influenced by a humid atmosphere. The surface layer is formed predominantly by copper hydroxide. The minor features of Cu 2p and O 1s are characteristic of the bulk bonding states. The valences of the Cu, Ca, and Sr atoms are close to 2+. The core electron binding energies (≈ 934 eV peak) are due to the 2p$\text{}_{3}\text{}_{/}\text{}_{2}$ 3d$\text{}^{10}$L$\text{}^{1}$ configuration of Cu(II) ions in the square planar coordination for both samples.
- Dostawca treści:
- Biblioteka Nauki
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