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Wyszukujesz frazę "65.40.gd" wg kryterium: Temat


Tytuł:
Entropy Change Calculations for Pure Gd and a Ni-Mn-Cu-Ga Heusler Alloy: Constant Field vs. Constant Temperature Experiment
Autorzy:
Ferenc, J.
Kowalczyk, M.
Wróblewski, R.
Cieślak, G.
Sielicki, K.
Leonowicz, M.
Kulik, T.
Tematy:
75.30.Sg
65.40.gd
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Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1402338.pdf  Link otwiera się w nowym oknie
Opis:
The magnetocaloric effect may be assessed indirectly by expressing it as the change in magnetic entropy in varying magnetic field, H, as the function of temperature, T. Magnetization, M=f(T,H), may be experimentally acquired from a series of isothermal measurements with variable field, or from a series of constant field measurements with variable temperature. The accuracy of magnetic entropy calculation depends on the number of series in these experiments. The aim of this work is to determine how little data is sufficient to obtain accurate results of magnetic entropy change calculations, on the basis of real, magnetocaloric materials. Pure gadolinium and a Ni-Mn-Cu-Ga Heusler alloy were studied. For both materials, the magnetic entropy change and relative cooling power were calculated from both experiments, with the decreasing number of experimental data. For both materials, the constant field experiment with only 6 field values provided only a 5% error of calculations, as compared to the experiment with 100 field values. The Arrott plots were also drawn for constant field mode with 6 field values, easily indicating the order of transition. Comparison of the calculation results suggests that the constant field mode magnetization measurement may be more accurate and faster than isothermal mode.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Si Substitution and Annealing on Magnetocaloric Properties in $TbCo_2$
Autorzy:
Janatova, M.
Poltierova Vejpravova, J.
Javorsky, P.
Prokleska, J.
Svoboda, P.
Danis, S.
Tematy:
65.40.Gd
75.30.Sg
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1813663.pdf  Link otwiera się w nowym oknie
Opis:
We report on magnetocaloric properties of the as-cast and annealed $TbCo_2$ with partial substitution of cobalt by silicon. The samples were characterized by powder X-ray diffraction and investigated by heat capacity measurements (8-300 K, in fields 0 T and 1 T). $TbCo_2$ undergoes a second-order type phase transition at $T_C$ = 240 K, from paramagnetic to ferrimagnetic state;similar behavior was revealed in the Si-doped compounds. The temperature dependence of magnetic entropy and the corresponding magnetocaloric effect were derived for all studied samples. The influence of the heat treatment and Si doping on magnetocaloric properties will be discussed in context of the analogue case $Er(Co_{1-x}Si_x)_2$.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Liquid Crystalline Polymorphism of 4-Alkyloxybenzylidene-4-Alkyloxyanilines and Entropic Effects of Their Phase Transitions
Autorzy:
Godzwon, J.
Sienkowska, M.
Galewski, Z.
Tematy:
64.70.M-
65.40.gd
64.70.pp
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Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1813170.pdf  Link otwiera się w nowym oknie
Opis:
This paper summarizes liquid-crystalline polymorphism of the asymmetrical 4-alkyloxybenzylidene-4'-alkyloxyanilines. In this group, containing 121 compounds, 6 types of mesophases were detected: nematic, smectic A, smectic C, smectic B, smectic I, and smectic G. Influence of both alkyl chain length on the type of mesophases and entropic effects of phase transitions are discussed.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties of $Dy_{11}Si_4In_6$
Autorzy:
Duraj, D.
Baran, S.
Jaworska-Gołąb, T.
Kalychak, Ya.
Przewoźnik, J.
Szytuła, A.
Tyvanchuk, Yu.
Tematy:
75.30.Kz
75.40.-s
75.40.Gb
65.40.gd
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1427191.pdf  Link otwiera się w nowym oknie
Opis:
Magnetic and specific heat measurements of $Dy_{11}Si_4In_6$ are reported. This compound crystallizes in the tetragonal $Sm_{11}Ge_4In_6$-type crystal structure (space group I4/mmm), in which Dy atoms occupy four different sites. The AC and DC magnetic measurements suggest complex magnetic properties. Below $T_{c}$ = 52 K magnetic ordering has a ferromagnetic component, while below 20 K a change of the properties is observed. Near the Curie temperature the magnetocaloric effect with the magnetic entropy change $\Delta S_{m}$ equal to 16.5 J/(kg K) is observed. The specific heat data indicate only the phase transition at 52 K.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic and structural studies into the effect of solvent exchange process in metal-organic framework MOF-76(Gd)
Autorzy:
Almáši, M.
Zeleňák, V.
Zeleňáková, A.
Tematy:
75.30.Sg
75.75.Fk
65.40.gd
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1054760.pdf  Link otwiera się w nowym oknie
Opis:
Effect of solvent exchange/absence on magnetic and structural properties of microporous metal-organic framework MOF-76(Gd) has been performed. Three compounds have been prepared and characterized: as synthesized MOF-76(Gd)-DMF, which containing DMF (N,N'-dimethylformamide) and H₂O molecules in the cavity system, activated complex without solvents, MOF-76(Gd) and water exchanged sample MOF-76(Gd)-H₂O. The structural study showed that compounds undergo structural changes after activation/exchange processes. Changes were mainly observed in the magnetic properties and distances between Gd...Gd ions: 4.718 Å for MOF-76(Gd)-DMF, 4.326 Å for MOF-76(Gd)-H₂O and 4.296 Å for MOF-76(Gd). The magnetic properties of the samples were studied by magnetic susceptibility χ_{M}(T) and magnetization M(H). The low positive value of the Weiss constant, Θ = 1.54 K in compound MOF-76(Gd)-DMF shows on a very weak ferromagnetic interaction. On the contrary, the negative values of Θ in complexes MOF-76(Gd) (-5.58 K) and MOF-76(Gd)-H₂O (-6.23 K) confirm the existence of antiferromagnetic exchange interaction between Gd(III) ions.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Scaling analysis of the magnetocaloric effect in Co/Au nanoparticles
Autorzy:
Hrubovčák, P.
Zeleňáková, A.
Zeleňák, V.
Franco, V.
Tematy:
75.30.Sg
75.75.Fk
65.40.gd
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1054838.pdf  Link otwiera się w nowym oknie
Opis:
The system of superparamagnetic Co/Au bimetallic nanoparticles of average diameter 7 nm was investigated with respect to its magnetocaloric properties. DC magnetic measurements revealed the presence of field dependent zero field cooled M(T) maximum (6-8 K) and significant zero field cooled/field cooled irreversibility at low temperatures in the system. Documented thermal hysteresis disallow standard magnetic entropy change calculation from isothermal M(H) data, thus we attempted to employ zero field cooled M(T) data for this purpose. Magnetic entropy change was calculated employing the Maxwell relation. In maximal field variation of 1 T relative high magnetic entropy change for nanoparticles Δ S_M ≈ 0.7 J/(kg K) at T =9 K was observed. The data collapsed onto single universal curve after proper axis rescaling.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Anisotropy of the Magnetocaloric Effect in the $Ni_{49.6}Mn_{27.6}Ga_{22.8}$ Single Crystal
Autorzy:
Wroblewski, R.
Sielicki, K.
Leonowicz, M.
Tematy:
65.40.gd
75.30.Gw
75.30.Sg
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1402315.pdf  Link otwiera się w nowym oknie
Opis:
The magnetocaloric effect anisotropy in the $Ni_{49.6}Mn_{27.6}Ga_{22.8}$ single crystal was investigated. In the examined alloy the structural phase transition and magnetic transition occur at room temperature and around 370 K, respectively. The magnetic entropy change, at those two temperatures, was determined on the basis of isothermal and isofield curves, recorded at fields up to 1200 kA/m (1.5 T) with temperature steps of 2.5 and 5 K. Although the calculated values of magnetic entropy change are relatively small, ≈0.7 J/(kg K), an anisotropy of the magnetocaloric effect is observed with a magnetic field applied along the main crystallographic directions of the single crystal. The magnetic entropy change at the structural phase transition depends on the orientation. The weakest magnetocaloric effect occurs when the field is applied along [1 0 0] direction whereas the highest magnetocaloric effect value is reached along [0 0 1] direction, which is an easy magnetization axis. Such behaviour can be explained with the high magnetocrystalline anisotropy of the martensitic phase. The magnetic entropy change value, at the structural phase transition, obtained for the polycrystalline specimen, is close to that for the [0 0 1] single crystal direction.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Nonstoichiometry on Magnetocaloric Effect in $(La_{0.7}Ca_{0.3})_{1 - x}Mn_{1+x}O_3$
Autorzy:
Sazanovich, A.
Pietosa, J.
Pashchenko, A.
Zubov, E.
Dyakonov, V.
Szymczak, H.
Tematy:
75.30.Sg
61.50.Nw
65.40.gd
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1419814.pdf  Link otwiera się w nowym oknie
Opis:
Magnetocaloric effect in $(La_{0.7}Ca_{0.3})_{1 - x}Mn_{1 + x}O_3$ manganites with x = 0, 0.1, 0.2 has been investigated. It is found a strong influence of nonstoichiometry caused by excessive manganese on the magnetic entropy change. The magnetocaloric effect was evaluated from the isothermal curves of spontaneous magnetization versus the applied magnetic field by using the well-known thermodynamical Maxwell relation. The maximum entropy value, $| \Delta S_{M}^\text{max} |,$ near the ferromagnetic-paramagnetic phase transition is shown to increase with the manganese content. The $La_{0.56}Ca_{0.24}Mn_{1.2}O_3$ manganite exhibits the largest $| \Delta S_{M}^\text{max} |$ value equal to $3.09 J kg^{-1} K^{-1}$ at 15 kOe near $T_{C}$ = 267 K. The magnetocaloric effect values obtained allow to propose that the studied manganites are promising materials for future cooling application.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heat Capacity Studies of $NdNi_4Si$ Compound
Autorzy:
Falkowski, M.
Reiffers, M.
Zapotoková, M.
Kowalczyk, A.
Toliński, T.
Gažo, E.
Tematy:
65.40.De
65.40.gd
71.20.Eh
71.70.-d
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1810401.pdf  Link otwiera się w nowym oknie
Opis:
The study of the heat capacity of the intermetallic compound $NdNi_{4}Si$ including the effect of the magnetic field is reported. This compound crystallizes in the hexagonal $CaCu_5$-type structure, space group P6/mmm. $NdNi_{4}Si$ is ferromagnetic with $T_C$ = 8 K and the saturation magnetic moment of 1.5 $μ_{B}$/f.u. at 4.2 K (in H = 9 T). The heat capacity was analyzed considering the electronic contribution, the Schottky anomaly, and the lattice contributions in the frames of the Debye model. The scheme of the energy levels created by the crystal electric field split is determined from the Schottky contribution to the specific heat. $NdNi_{4}Si$ was characterized by the electronic heat capacity coefficient γ = 85 mJ/(mol $K^2$) and the Debye temperature $Θp_D$ = 325 K.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrical Characterization of Interdigitated Humidity Sensors Based on CNT Modified Calixarene Molecules
Autorzy:
Özbek, C.
Culcular, E.
Okur, S.
Yılmaz, M.
Kurt, M.
Tematy:
66.30.je
65.40.gp
65.40.gk
65.40.gd
64.70.fm
64.10.+h
51.10.+y
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Powiązania:
https://bibliotekanauki.pl/articles/1400035.pdf  Link otwiera się w nowym oknie
Opis:
In this study, we report on the optimization and characterization of chloroform soluble calix[4]arene derivative as a humidity sensor based on electrical properties. Due to the fact that calix[4]arene molecules are nonconductive, we modified the calix[4]arene molecules with carbon nanotubes with electrostatic bond in order to increase the conductance of calix[4]arene molecule (5,11,17,23-tetra-ter-butyl-25,27-dehydrazinamidcarbonilmetoxy-26,28-dehydroxy-kalix[4]aren). Using photolithography technique, we fabricated interdigitated gold electrodes with 3 micrometers separation to investigate the electrical properties of carbon nanotubes modified calix[4]arene molecule where we used dropcast method to form a thin film of carbon nanotubes modified calix[4]arene molecule on the gold electrodes. Our reproducible experimental results indicated that the chloroform soluble carbon nanotubes modified calix[4]arene films have great potential for humidity sensing applications at room temperature operations.
Dostawca treści:
Biblioteka Nauki
Artykuł

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