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Wyszukujesz frazę "cadmium(II)" wg kryterium: Temat


Tytuł:
Water Purification from Ions of Cadmium (II) Using a Bio-Plateau
Autorzy:
Lapan, Oksana
Mikhyeyev, Oleksandr
Madzhd, Svitlana
Dmytrukha, Tetyana
Cherniak, Larysa
Petrusenko, Valentyna
Tematy:
phytoremediation
bio-plateau
terrestrial plant
cadmium(II)
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Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Powiązania:
https://bibliotekanauki.pl/articles/123841.pdf  Link otwiera się w nowym oknie
Opis:
The study was conducted with the purpose of experimentally developing the method of water purification from ions of cadmium (II) using a new design of a bio-plateau, which is based on the use of terrestrial plants. In order to construct the bio–plateau, the following chemically inert floating materials were used as the substrate: perlite, expanded clay, granular foam, vermiculite, cork, on top of which the seeds of higher terrestrial plants were placed. The experimental data showed that foam was the best of the tested substrates, and of plants – barley, oats, corn and rye. The constructed bio-plateau was placed into tanks with a solution of cadmium on the 9th day of incubation to study the cleaning efficiency of terrestrial plants on the aquatic environment. Determination of the residual concentration of cadmium was performed with the method of AAC at λ=228.8. As a result, it was found that rye showed the best sorption properties of the tested plants. The influence of additional aeration and pH of the medium on the degree of water purification was established. The highest treatment efficiency was observed in the variant of a bio-plateau with aeration and at a pH of 8-9. The study shows the possibility of using terrestrial plants for the phytoremediation of water bodies.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Lead(II) removal from aqueous solutions by solvent extraction with tetracarboxylresorcin[4]arene
Autorzy:
Konczyk, J.
Kozlowski, C.
Walkowiak, W.
Tematy:
solvent extraction
lead(II)
zinc(II)
cadmium(II)
resorcinarene
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Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Powiązania:
https://bibliotekanauki.pl/articles/110670.pdf  Link otwiera się w nowym oknie
Opis:
A novel tetracarboxylresorcin[4]arene was synthesized and its selective complexing ability towards Pb(II) ions was examined. The influence of several parameters such as pH of aqueous phase, agitation time, extractant and modifier concentrations on solvent extraction of Pb(II) ions from the aque-ous nitrate phase into chloroform organic phase was studied. The stoichiometry of the formed metal-ligand complexes was established by slope analysis. Pb(II) ions were quantitatively extracted in the form of 2:1 Pb(II)-resorcin[4]arene complex from aqueous solutions of pH 5.5 to the solution of ligand in chloroform. Competitive solvent extraction experiments in the presence of Zn(II) and Cd(II) ions were also carried out and high selectivity of the extractant towards Pb(II) over Zn(II) and Cd(II) was found. The selectivity order was: Pb(II) >> Cd(II) > Zn(II).
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
N-(diethylthiophosphoryl)-aza[18]crown-6: synthesis and ability of solvent extraction toward lead(II), zinc(II) and cadmium(II) metal cations
Autorzy:
Kozlowska, J.
Miroshnichenko, S.
Tematy:
crown ethers
solvent extraction
lead(II)
zinc(II)
cadmium(II)
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Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Powiązania:
https://bibliotekanauki.pl/articles/346955.pdf  Link otwiera się w nowym oknie
Opis:
This work presents the synthesis of a strongly hydrophobic, functionalized monaza crown ether, i.e., lariat ether, namely N-(diethylthiophosphoryl)-aza[18]crown-6 and its application as ion extractant in solvent extraction systems. The synthesis of thiophosphorylated aza[18]crown-6 was performed with good yield. Separation systems have been successfully developed to extract Pb(II), Cd(II) and Zn(II) into organic phase, i.e., chloroform with the crown ethers: aza[18]crown-6 and N-(diethylthiophosphoryl)-aza[18] crown-6 as extractants. The selectivity order in both crown ethers was Pb(II) >> Cd(II) > Zn(II). The obtained results suggest that N-(diethylthiophosphoryl)-aza[18]crown-6 can be used for the selective removal of Pb(II) at lower pH values than aza[18]crown-6.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction properties of tetraheptylresorcin[4]arenes in relation to Cr(III) ions
Autorzy:
Konczyk, J.
Miroshnychenko, S.
Kozlowski, C.
Tematy:
solvent extraction
resorcin[4]arenes
chromium(III)
cadmium(II)
zinc ions
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Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Powiązania:
https://bibliotekanauki.pl/articles/109751.pdf  Link otwiera się w nowym oknie
Opis:
Resorcin[4]arene-based ligand bearing four heptyl chains at the lower rim of the molecule was prepared and modified by four tetradietoxyphosphoryl groups in the upper rim. The compounds obtained were characterized by NMR spectroscopy and their extractability toward chromium(III) ions was studied. The influence of process parameters such as the pH of aqueous phase, agitation time and also extractant’s structure and concentration on efficiency of Cr(III) ions solvent extraction is presented. The highest yield of Cr(III) solvent extraction was obtained for two-hour agitation time of 5.010−4 M metal solution of pH 5.0 and 5.010−3 M chloroform solution of the tetradietoxyphosphorylated derivative of heptyl-resorcin[4]arene. Under optimal conditions, competitive solvent extraction of Cr(III), Zn(II), and Cd(II) ions was performed and separation factor values were established as 77.0 and 24.9 for Cr(III)/Cd(II) and Cr(III)/Zn(II) ions pairs, respectively. The stoichiometry of formed metal-ligand complexes 1:1 was found by classical slope analysis method.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zinc(II) selective removal from other transition metal ions by solvent extraction and transport through polymer inclusion membranes with D2EHPA
Autorzy:
Ulewicz, M.
Walkowiak, W.
Pośpiech, B.
Tematy:
polymer inclusion membrane
solvent extraction
zinc(II)
cobalt(II)
nickel(II)
copper(II)
cadmium(II)
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Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Powiązania:
https://bibliotekanauki.pl/articles/346997.pdf  Link otwiera się w nowym oknie
Opis:
An experimental investigation concerns zinc(II), cobalt(II), nickel(II), copper(II) and cadmium(II) ions separation from aqueous chloride solutions by solvent extraction and transport through polymer inclusion membrane (PIM) processes. The selective transport of metal ions from the aqueous chloride source phase through PIM containing cellulose triacetate (support), o-nitrophenyl pentyl ether (plasticizer) and di(2-ethylhexyl)phosphoric acid (ion carrier) is shown. Zn(II) can be effectively removed from dilute aqueous chloride solutions by its transport through PIMs with di(2-ethylhexyl)phosphoric acid as the ionic carriers into 1.0 M HCl as the receiving phase. The transport selectivity of Zn(II) over Co(II), Ni(II), Cu(II) and Cd(II) decreases while the pH of the solution increases in the source phase. Also, by solvent extraction, Zn(II) can be selectively removed from dilute aqueous chloride solutions.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Transport of transition metal ions through polymer inclusion membranes with Cyanex 301
Autorzy:
Ulewicz, M.
Tematy:
polymer inclusion membrane
zinc(II)
cadmium(II)
copper(II)
cobalt(II)
nickel(II)
Cyanex 301
Pokaż więcej
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Powiązania:
https://bibliotekanauki.pl/articles/347064.pdf  Link otwiera się w nowym oknie
Opis:
The selective transport of zinc(II) and cadmium(II) ions from aqueous chloride or sulfate source phase through polymer inclusion membranes (PIM) containing cellulose triacetate (support), o-nitrophenyl pentyl ether (plasticizer) and di(2,4,4-trimethylpentyl)dithiophosphinic acid - Cyanex 301 (ion carrier) is shown. Zn(II) and Cd(II) ions can be effectively removed from dilute chloride and sulfate aqueous solutions into 1.0 M HCl or H2SO4 as the receiving phase. The separation coefficients were practically constant for acid concentrations in the receiving phase ranging from 0.01 to 1.0 M Copper(II), zinc(II), cadmium(II), cobalt(II), and nickel(II) ions removal from aqueous chloride solutions in transport through PIMs is also shown. These metal ions can be effectively removed from dilute aqueous chloride solutions in transport through PIMs with di(2,4,4-trimethylpentyl)dithiophosphinic acid as the ionic carriers into 1.0 M HCl. The selectivity coefficients of Cu(II) over Zn(II), Cd(II), Co(II) and Ni(II) were low and decreased with an increase in the pH of source aqueous phase.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of the steric effect of the carrier molecule in the polymer inclusion membranes for the separation of cobalt(II), nickel(II), copper(II), and zinc(II) ions
Autorzy:
Radzyminska-Lenarcik, E.
Ulewicz, M.
Tematy:
polymer inclusion membrane
separation ions
steric effect
copper(II)
cobalt(II)
nickel(II)
cadmium(II)
zinc(II)
alkylimidazole
Pokaż więcej
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/778754.pdf  Link otwiera się w nowym oknie
Opis:
In this study, palladium-modified nickel foam substrate was applied to examine ethanol oxidation reaction (EOR) in 0.1 The transport of cobalt(II), nickel(II), copper(II), and zinc(II) ions from chloride solutions across polymer inclusion membranes (PIMs), which 1-heptylimidazole (1̲) or 1-heptyl-2-methylimidazole (2̲) or 1-heptyl-4-methylimidazole (3̲) as the ion carrier was reported. The steric effect for carriers 2̲&enspand 3̲&enspdecreases the transport of all ions except Cu(II). The initial fluxes of metal ions transport across PIMs with the 1̲- 2̲&enspdecrease in the sequence: Cu(II) > Zn(II) > Co(II) > Ni(II), whereas for 3 they were Cu(II) > Zn(II) > Ni(II) > Co(II). The highest recovery values were obtained for Cu(II), this being 99 and 85% for carrier 1̲&enspand 2̲, respectively. In both membranes the degree of deposition of the Zn(II) ions was comparable. Zn(II), Co(II) and Cd(II) ions, which form complexes with coordination numbers 4 and 6, are more easily recovered with the use of carriers 2̲&enspand 3̲. Ni(II) ions, which form complexes with coordination number 6 only, practically remain in the feeding phase. PIMs with alkylimidazoles were characterized by non-contact atomic force microscopy.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Novel eight-coordinated Cd(II) complexes with two homologous pyridine alcohols : crystal structure, spectroscopic and thermal properties
Autorzy:
Jabłońska-Wawrzycka, Agnieszka
Stadnicka, Katarzyna
Zienkiewicz, Małgorzata
Masternak, Joanna
Opis:
Two novel cadmium(II) complexes with homologous pyridine alcohols: $[Cd(2-EtOHPy)_{2}(NO_{3})_{2}]$ (1) and $[Cd(2-EtOHPy)_{2}(NO_{3})_{2}]$ (2) have been prepared and characterized by elemental analysis, X-ray crystallo- graphic studies, spectroscopic (IR, $^{1}\textrm{H}$ and $^{13}\textrm{C}$ NMR) and thermal properties. IR, NMR and X-ray analysis have confirmed a bidentate fashion of coordination of heteroaromatic alcohols with Cd(II) ions. 2-MeO- HPy bound directly to the central ion by N, O-donor atoms giving five-membered chelate ring but 2- EtOHPy formed less stable six-membered chelate ring. In the complex (1) and (2) bidentate nitrate ligands are arranged in cis position for organic ligands. In both cases cadmium(II) ions are eight-coordi- nated and shape of coordination polyhedral can be described as pseudo-dodecahedron ($CdN_{2}O_{6}$ chromo- phore type). The crystal packing of Cd(II) complexes are stabilized by intermolecular classical hydrogen bonds of O–H$\cdots$O and non-classical C–H$\cdots$O type. In addition, there are $\pi$–$\pi$ stacking interactions between almost parallel-displaced pyridine rings of 2-hydroxymethylpyridine in the two neighbouring complex (1) molecules but the hydrogen interactions in (2) are formed by C–H donor group of Py rings and $\pi$-electron system of neighbouring one.
Dostawca treści:
Repozytorium Uniwersytetu Jagiellońskiego
Artykuł

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