- Tytuł:
- How to avoid mass transfer limitations in ozonation kinetics of phenylphenol isomers?
- Autorzy:
-
Olak-Kucharczyk, M.
Ledakowicz, S. - Tematy:
-
phenylphenol isomers
ozonation in homogenous system ozonation kinetics
competition kinetics
classical kinetics
ozonowanie w jednorodnym systemem kinetyki ozonowania
kinetyka konkurencji
kinetyka - Pokaż więcej
- Wydawca:
- Polska Akademia Nauk. Czasopisma i Monografie PAN
- Powiązania:
- https://bibliotekanauki.pl/articles/185599.pdf Link otwiera się w nowym oknie
- Opis:
- Ozonation is a heterogeneous process of chemical absorption often controlled by a gas-liquid mass transfer rate. This paper presents the results of kinetics in a reaction between phenylphenol isomers and ozone. The degradation of phenylphenol isomers during ozonation proceeds quite fast. In order to avoid the influence of mass transfer limitati on the kinetics experiments were conducted in a homogenous liquid-liquid system. The second-order rate constantswere determined using classical and competition methods, which are especially recommended for fast reactions. The determined rate constants at pH 2 using the two different methods are almost the same. The increase of pH causes an increase of rate constants for the reaction of phenylphenol isomers with ozone.
- Dostawca treści:
- Biblioteka Nauki
Artykuł