Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Pedagogiczna Biblioteka Wojewódzka im. Komisji Edukacji Narodowej w Lublinie Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaPedagogiczna Biblioteka Wojewódzka im. Komisji Edukacji Narodowej w Lublinie
Zmień bibliotekę

Wyszukujesz frazę "energetic material" wg kryterium: Temat

  Lista filtrów
Wyrównaj
Wyświetlanie 1-10 z 15
Tytuł:
Three Insensitive Energetic Co-crystals of 1-Nitronaphthalene, with 2,4,6-Trinitrotoluene (TNT), 2,4,6-Trinitrophenol (Picric Acid) and D-Mannitol Hexanitrate (MHN)
Autorzy:
Hong, D.
Li, Y.
Zhu, S.
Zhang, L.
Pang, C.
Tematy:
co-crystal
insensitive energetic material
crystal structure
explosive properties
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/1063066.pdf  Link otwiera się w nowym oknie
Opis:
Co-crystallization is proposed as an effective method to alter the physicochemical properties of energetic materials, e.g. density, sensitivity and solubility. As reported in this paper, it was found that 1-nitronaphthalene could form cocrystals with TNT, picric acid and MHN in a 1:1 molecular ratio. The sensitivity and thermal stability of the 1-nitronaphthalene co-crystals was greatly improved compared with that of pure TNT, picric acid and MHN. In addition, the melting points of TNT, picric acid and MHN were lowered through co-crystallization with 1-nitronaphthalene. The electrostatic potential surface of 1-nitronaphthalene, calculated by the DFT method, showed that the electron-rich 1-nitronaphthalene has a tendency to be a proton donor and to co-crystallize with other energetic materials. The structures of the co-crystals of 1-nitronaphthalene with TNT and picric acid were characterized by single crystal X-ray diffraction (SXRD). The 1-nitronaphthalene/MHN co-crystal was studied by powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC) and FTIR.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization and Application of Al/Ni Reactive Multilayers in Exploding Foils
Autorzy:
Wang, T.
Zeng, Q.
Li, M.
Tematy:
energetic material
Al/Ni reactive multilayer foils
bilayer thickness
exploding foil initiator
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/358516.pdf  Link otwiera się w nowym oknie
Opis:
A self-propagating reaction achieved by initiating an Al/Ni reactive multilayer foil can generate significant heat. The interdiffusion rate of the reactants plays an important role in the foils properties and is mainly affected by premixing and the bilayer thickness. The present research aims to characterize Al/Ni multilayer foils and to investigate their influence on an exploding foil initiator. Samples with different bilayer thicknesses were fabricated by magnetron sputtering. The heat released and the flame velocity were characterized. Foils with a stored energy of about 1100 J/g were prepared and the heat released revealed the existence of a 4 nm premixing layer. The analytical model proposed by Mann was employed to match the measured flame velocities; the fitted model showed good agreement with the experimental results. To make a comparison, Cu and Al/Ni exploding foils with the same bridge size were fabricated and tested in the identical discharge circuit. The results showed that the energy deposition ratio of an Al/Ni foil was 67-69%, while the value for Cu was only 39-45%, which indicated that Al/Ni multilayers could effectively increase the energy utilization of an initiator. Larger average flyer velocities were also observed with the Al/Ni initiators.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Crystal Structure, and Properties of a Novel, Highly Sensitive Energetic, Coordination Compound: Iron (II) Carbohydrazide Perchlorate
Autorzy:
Liu, R.
Zhou, Z.
Qi, S.
Yang, L.
Wu, B.
Huang, H.
Zhang, T.
Tematy:
iron (II) carbohydrazide perchlorate
energetic material
high
sensitivity
DFT
energy gap
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/358343.pdf  Link otwiera się w nowym oknie
Opis:
A single crystal of iron (II) carbohydrazide perchlorate [FeII (CHZ)3](ClO4)2 (FeCP), a novel, lead-free, energetic coordination compound, was synthesized and its structure determined by X-ray single crystal diffraction for the frst time. The crystal belongs to the monoclinic system P2(1)/n space group, with a = 1.0066(2) nm, b = 0.8458(2) nm, c = 2.1194(4) nm, β = 100.693(3)° and Z = 4. The central Fe(II) ion is coordinated to three bidentate carbohydrazide units through the carbonyl oxygen atom and an amino nitrogen atom, forming a six-coordinated, non-centrosymmetric complex cation. The thermal analyses by differential scanning calorimetry and thermogravimetry show that the onset temperature of thermal decomposition (152.7 °C) and the critical temperature of thermal explosion of FeCP (161.2 °C) are both much lower than those of other transition metal carbohydrazide perchlorate compounds, and also those of some other primary explosives in service. FeCP has a high enthalpy of combustion, as measured by oxygen bomb calorimetry. The impact, friction and fame sensitivity tests indicate that FeCP is extremely sensitive and hazardous. Unexpected explosions occurred even during the operational processes. In order to explore the intrinsic cause of these explosions, theoretical calculations of the orbital energies were performed based on DTF. These results reveal that the impact sensitivity is positively correlated with the energy gap between HOMO and LUMO: the smaller energy gap results in the higher impact sensitivity.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Role of Thermochemical Decomposition in Energetic Material Initiation Sensitivity and Explosive Performance
Autorzy:
Shackelford, S. A.
Tematy:
energetic material
thermochemical decomposition
kinetic deuterium isotope effect
KDIE
initiation sensitivity
performance
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/358845.pdf  Link otwiera się w nowym oknie
Opis:
Catastrophic initiation of an energetic material consists of a complex, interactive, sequential train of mechanistic mechanical, physical, and chemical processes which occur over a finite time period and proceed from macroscopic into sub-microscopic composition levels (bulk > crystalline > molecular > atomic). Initiation results when these processes proceed at a rate which generates sufficient energy (heat) to reach a threshold stage within this finite time period. Thus, the rate at which these mechanistic processes occur defines initiation sensitivity and affects performance. Thermochemical decomposition processes regulate the rate at which heat energy is released at the molecular level, and therefore to some extent, control energetic material initiation sensitivity and performance characteristics. Kinetic deuterium isotope effect (KDIE) data, obtained during the ambient pressure thermochemical decomposition process, identifies the mechanistic rate-controlling bond rupture which ultimately regulates the energy release rate of a given energetic material. This same rate-controlling bond rupture also appears as a significant rate-limiting feature in higher order deflagration, combustion, and explosion phenomena. The effect the KDIE-determined rate-controlling bond rupture exerts on initiation sensitivity, and its potential influence in combustion and explosion performance is delineated.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Nanomaterials on Thermal Stability of 1,3,6,8-Tetranitro Carbazole
Autorzy:
Pourmortazavi, S. M.
Rahimi-Nasrabadi, M.
Rai, H.
Jabbarzadeh, Y.
Javidan, A.
Tematy:
thermal stability
nanomaterial effect
decomposition kinetics
1,3,6,8-tetranitro carbazole
energetic material
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/358744.pdf  Link otwiera się w nowym oknie
Opis:
1,3,6,8-tetranitro carbazole (TNC) as a secondary explosive is used in composite explosive formulations in order to reduce the sensitivity and increase the stability of the explosive composites. In this work, the thermal stabilities of pure TNC and its nanocomposites prepared via three different nanoparticles were studied by thermal analysis, i.e. differential scanning calorimetery (DSC) and thermogravimetry (TG) techniques. Thermal analysis data revealed that the thermal behavior of pure TNC is significantly different from the nanocomposites studied. Pure TNC decomposed completely during a single step in the temperature range 385-425 °C. However, the addition of nanoparticles to the TNC powder leads to higher thermal stability in comparison with the pure TNC. The decomposition kinetics of TNC and its nanocomposites were studied by non-isothermal DSC at several heating rates. Thermokinetic and thermodynamic parameters corresponding to the thermal decomposition of pure TNC and nanocomposites were computed and compared. The results showed that the addition of nanoparticles to the TNC powder has a considerable effect on the thermal stability of the explosive.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal Expansion of Explosive Molecular Crystals: Anisotropy and Molecular Stacking
Autorzy:
Qian, W.
Zhang, C.
Xiong, Y.
Zong, H.
Zhang, W.
Shu, Y.
Tematy:
energetic material
anisotropic thermal expansion
molecular stacking
molecular dynamics simulation
density functional theory method
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/358262.pdf  Link otwiera się w nowym oknie
Opis:
Molecular dynamics simulations of three typical explosive crystals, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), 1,1-diamino-2,2- dinitroethene (FOX-7) and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB), were carried out under NPT ensemble and selected force field. The equilibrium structures at elevated temperatures were obtained, which show that the stacking behaviour of the molecules does not change with temperature. The coefficient of thermal expansion (CTE) values were calculated by linear fitting methods, and the results show that the CTE values are close to the experimental results and are anisotropic. The total energies of the cells expanding along each single crystallographic axis were calculated by the periodic density functional theory method, indicating that the energy change rates are anisotropic, and correlation equations of the energy change vs. CTE values were established. The essence of the anisotropy of the explosive crystal’s thermal expansion was compared and elucidated.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania nad modyfikacją składu heterogenicznego paliwa dla dwuzakresowego silnika rakietowego
Studies on Modification of Formulations of Composite Solid Propellant for Dual Thrust Rocket Motor
Autorzy:
Florczak, B.
Cholewiak, A.
Tematy:
stałe heterogeniczne
paliwo rakietowe
dwuzakresowy silnik rakietowy
materiał wysokoenergetyczny
composite solid propellant
dual thrust rocket motor
high energetic material
Pokaż więcej
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Powiązania:
https://bibliotekanauki.pl/articles/403420.pdf  Link otwiera się w nowym oknie
Opis:
W pracy przedstawiono wyniki z badań zmodyfikowanych ładunków napędowych dla dwuzakresowego silnika rakietowego. Modyfikacja polegała na optymalizacji składu heterogenicznego paliwa rakietowego na bazie nadchloranu amonu jako utleniacza i lepiszcza na bazie ciekłego kauczuku PBAN z dodatkiem Al. W rezultacie otrzymano paliwo z lepszymi parametrami energetycznymi w porównaniu do paliwa odniesienia.
This paper presents the results of investigations of modified composite solid propellant charges for the dual made rocket motor. The modification has been done by selection of composition of the heterogeneous solid propellant made on the base of ammonium perchlorate as an oxidizer and the binder on the base of liquid rubber PBAN. As a result of modifications it was obtained the composite solid rocket propellant of better energetic and ballistic properties in comparison with the reference composite propellant.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
N-Nitropyridinium Nitrate: An Efficient Nitrating Agent for the Synthesis of 2-[Butyl(nitro)amino]ethyl Nitrate (n-BuNENA)
Autorzy:
Bayat, Y.
Esmailmarandi, F.
Tematy:
2-[butyl(nitro)amino]ethyl nitrate (n-BuNENA)
zeolite
N-nitropyridinium nitrate
plasticizer
energetic material
Pokaż więcej
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Powiązania:
https://bibliotekanauki.pl/articles/358046.pdf  Link otwiera się w nowym oknie
Opis:
The present investigation focused on the synthesis of 2-[butyl(nitro)amino]ethyl nitrate (n-BuNENA), by the nitration of N-butylethanolamine. For this purpose, various nitrating agents were studied and N-nitropyridinium nitrate was found to be a good nitrating agent. Short reaction time, ease of handling, performance of the reaction in one step and good yield are the main aspects of the present method. It also lead to 75% yield, which is a higher yield than by other methods. The purity of the product was evaluated by HPLC analysis, and its identity was confirmed by IR and 1H NMR spectroscopy.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energetic loading of forage harvester working units depending on cutting length of the plant material
Obciążenia energetyczne zespołów roboczych sieczkarni polowej w zależności od długości cięcia materiału roślinnego
Autorzy:
Chlebowski, J.
Klonowski, J.
Tematy:
energetic load
forage harvester
cutting
plant material
Pokaż więcej
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Powiązania:
https://bibliotekanauki.pl/articles/56299.pdf  Link otwiera się w nowym oknie
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 15

Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies