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Wyszukujesz frazę "methanation" wg kryterium: Temat


Wyświetlanie 1-8 z 8
Tytuł:
Effect of the ruthenium loading and barium addition on the activity of ruthenium/carbon catalysts in carbon monoxide methanation
Autorzy:
Truszkiewicz, Elżbieta
Raróg-Pilecka, Wioletta
Zybert, Magdalena
Wasilewska-Stefańska, Malwina
Topolska, Ewa
Michalska, Kamila
Tematy:
CO methanation
ruthenium catalyst
barium
carbon support
Pokaż więcej
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/778885.pdf  Link otwiera się w nowym oknie
Opis:
A group of supported ruthenium catalysts was prepared and tested in methanation of small CO amounts (7000 ppm) in hydrogen-rich streams. High surface area graphitized carbon (484 m2/g) was used as a support for ruthenium and RuCl3 was used as a Ru precursor. Some of the Ru/C systems were additionally doped with barium (Ba(NO3)2 was barium precursor). The catalysts were characterized by the chemisorption technique using CO as an adsorbate. To determine the resistance of the catalysts to undesired carbon support methanation, the TG-MS experiments were performed. They revealed that the barium addition inhibits support losses. The studies of CO methanation (fl ow reactor, atmospheric pressure) have shown that some of the supported ruthenium catalysts exhibit high activities referred to the metal mass. The catalytic properties of ruthenium proved to be dependent on metal dispersion. Some of the Ru/C and Ba-Ru/C systems exhibit higher activity in CO hydrogenation than the commercial nickel-based catalyst.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of heating rate and solvent on Ni-based catalysts prepared by solution combustion method for syngas methanation
Autorzy:
Zeng, Yan
Ma, Hongfang
Zhang, Haitao
Ying, Weiyong
Fang, Dingye
Tematy:
nickel catalysts
syngas methanation
solution combustion method
Pokaż więcej
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/779390.pdf  Link otwiera się w nowym oknie
Opis:
Ni-Al2O3 catalysts prepared by solution combustion method for syngas methanation were enhanced by employing various heating rate and different solvent. The catalytic properties were tested in syngas methanation. The result indicates that both of heating rate and solvent remarkably affect Ni particle size, which is a key factor to the catalytic activity of Ni-Al2O3 catalysts for syngas methanation. Moreover, the relationship between Ni particle size and the production rate of methane per unit mass was correlated. The optimal Ni-Al2O3 catalyst prepared in ethanol at 2°C/min, achieves a maximum production rate of methane at the mean size of 20.8 nm.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalysts preparation and investigation: laboratory exercise for students
Autorzy:
Zawadzki, Witold
Tematy:
laboratory course
catalysts preparation
TPR
TG
CO2 methanation
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Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Powiązania:
https://bibliotekanauki.pl/articles/2079940.pdf  Link otwiera się w nowym oknie
Opis:
Catalysts preparation, investigation its basic properties, activity and selectivity measurements in carbon dioxide methanation reaction was proposed as laboratory course for international students doing a period of study at Maria Curie-Sklodowska University within the frame of the Erasmus mobility programme.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
CO2 Hydrogenation to Methane over Ni-Catalysts: The Effect of Support and Vanadia Promoting
Autorzy:
Serwicka, Ewa M.
Krysa, Mikolaj
Lew, Agata
Pieta, Izabela S.
Pieta, Piotr
Kowalik, Pawel
Lewalska-Graczyk, Agnieszka
Gajek, Arkadiusz
Lisowski, Wojciech
Antoniak-Jurak, Katarzyna
Mrdenovic, Dusan
Nowakowski, Robert
Sroka-Bartnicka, Anna
Wydawca:
MDPI
Cytata wydawnicza:
Pieta, I.S.; Lewalska-Graczyk, A.; Kowalik, P.; Antoniak-Jurak, K.; Krysa, M.; Sroka-Bartnicka, A.; Gajek, A.; Lisowski, W.; Mrdenovic, D.; Pieta, P.; et al. CO2 Hydrogenation to Methane over Ni-Catalysts: The Effect of Support and Vanadia Promoting. Catalysts 2021, 11, 433. https://doi.org/10.3390/catal 11040433
Opis:
Within the Waste2Fuel project, innovative, high-performance, and cost-effective fuel production methods are developed to target the “closed carbon cycle”. The catalysts supported on different metal oxides were characterized by XRD, XPS, Raman, UV-Vis, temperature-programmed techniques; then, they were tested in CO2 hydrogenation at 1 bar. Moreover, the V2O5 promotion was studied for Ni/Al2O3 catalyst. The precisely designed hydrotalcite-derived catalyst and vanadia-promoted Ni-catalysts deliver exceptional conversions for the studied processes, presenting high durability and selectivity, outperforming the best-known catalysts. The equilibrium conversion was reached at temperatures around 623 K, with the primary product of reaction CH4 (>97% CH4 yield). Although the Ni loading in hydrotalcite-derived NiWP is lower by more than 40%, compared to reference NiR catalyst and available commercial samples, the activity increases for this sample, reaching almost equilibrium values (GHSV = 1.2 × 104 h–1, 1 atm, and 293 K).
Funding: This research was supported by receiving funding from the Foundation for Polish Science grant no POWROTY/2016-1/5 Waste into fuel–catalyst and process development for waste biomass valorization. ISP, PP extend their sincere appreciation to NAWA The Polish National Agency for Academic Exchange trough Bekker grants PPN/BEK/2019/1/00348 “C1-C4 alkanes to oxygenated fuel electrochemical transformation” and PPN/BEK/2019/1/00345 “Nanostructured carbon-based materials doped with metal nanoparticles as catalytic electrode materials for CO2 electoreduction with the use of surface-plasmon enhancement”. ISP gratefully acknowledges the support from French Government project “Catalytic conversion of CO2 to hydrocarbons: the Ni-V catalyst selectivity and durability in in plasma assisted hydrogenation of CO2 to methane.” The research activity of D.M. was supported by funds from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No. 711859 and by financial resources for science in the years 2017–2021 awarded by the Polish Ministry of Science and Higher Education for the implementation of an international co-financed project.
Dostawca treści:
Repozytorium Centrum Otwartej Nauki
Artykuł
Tytuł:
Preparation and characterisation of Pd nanocatalyst supported on nickel mesh
Autorzy:
Tomiczek, B.
Szindler, Marek
Łukowiec, D.
Pawlyta, M.
Nuckowski, P.
Lukaszkowicz, K.
Krzywiecki, M.
Kříž, A.
Basiaga, M.
Polański, J.
Tematy:
nanotechnology
nanoparticles
nanocatalyst
renewable energy
methanation
nanotechnologia
nanocząsteczki
nanokatalizator
energia odnawialna
metanizacja
Pokaż więcej
Wydawca:
Stowarzyszenie Komputerowej Nauki o Materiałach i Inżynierii Powierzchni w Gliwicach
Powiązania:
https://bibliotekanauki.pl/articles/59122463.pdf  Link otwiera się w nowym oknie
Opis:
The primary aim of the publication is to show the possibility of the synthesis of palladium nanoparticles directly on the nickel molecular mesh. A combination of chemical and physicochemical methods was used. Design/methodology/approach Palladium chloride was chosen as the precursor of palladium nanoparticles, dissolved in alcohol, water or a mixture thereof. Surface topography studies of the prepared nanoparticles were made using a scanning electron microscope, Supra 35 (Zeiss’s company), and transmission electron microscope S/TEM TITAN 80-300 (FEI company). Qualitative studies were performed using spectroscopy of scattered X-ray energy using the Energy Dispersive Spectrometer to define the chemical composition of prepared nanocatalysts. The chemical states of the elements were analysed using X-ray photoelectron spectroscopy. Nanocatalyst structures were identified using X-ray crystallography. Findings Using such methods proved that the obtained material is Pd-Ni synthesised using a mixture of alcohol and water assisted by ultrasound. Nanoparticles with oval shapes and diameters below 10 nm were obtained. Research limitations/implications During the tests, it was decided to abandon the use of the ascorbic acid reducer, which, combined with the temperature, had a negative impact on the nickel substrate. Practical implications Nanocatalyst has been achieving a gradually increasing interest from researchers in environmental areas. The developed materials can be used in low-temperature carbon dioxide methanation. Originality/value The results provide a novel road for designing and developing efficient, low-cost, and low-temperature double metallic catalysts.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trends in Biogas Technologies
Autorzy:
Busch, G.
Grossmann, Jochen
Tematy:
biogas technologies
flexible operation
biodegradable waste
phosphorus and nitrogen recovery
methanation
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Wydawca:
Gdańska Szkoła Wyższa
Powiązania:
https://bibliotekanauki.pl/articles/1190171.pdf  Link otwiera się w nowym oknie
Opis:
The presentation is meant to give a short overview on the state of the development of biogas technologies with special emphasis on the situation in Germany. Although the share of biogas based electrical energy among other types of renewable energies has become smaller, it still plays an important role for the compensation of fluctuating alternative energies and for the recycling of important substances like fertilisers as well. The growth of biogas capacities is limited due to the limited abundance of substrates. But newer technologies allow the biochemical production of biogas from carbon dioxide and hydrogen without any organic matter. Most probably, such processes will have the potential to change the common practise of biogas upgrading at least.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of renewable energy in the form of methane via electrolytic hydrogen generation
Zastosowanie odnawialnej energii w formie metanu na drodze elektrolitycznej produkcji wodoru
Autorzy:
Hashimoto, K.
Kumagai, N.
Izumiya, K.
Takano, H.
Żabiński, P. R.
El-Moneim, A. A.
Yamasaki, M.
Kato, Z.
Akiyama, E.
Habazaki, H.
Tematy:
energia odnawialna
podaż metanu
recykling CO2
elektrolityczne wytwarzanie wodoru
gaz syntezowy
wyczerpanie paliwa
przetrwanie ludności świata
renewable energy
methane supply
CO2 recycling
electrolytic hydrogen generation
CO2 methanation
syngas methanation
fuel depletion
survival of world population
Pokaż więcej
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Powiązania:
https://bibliotekanauki.pl/articles/350838.pdf  Link otwiera się w nowym oknie
Opis:
Extrapolation of world energy consumption from 1990 to 2010 indicates the complete exhaustion of world reserves of oil, natural gas, uranium and coal by 2040, 2043, 2046 and 2053, respectively. For the survival of all people in the whole world, intermittent and fluctuating electricity generated from renewable energy should be supplied in the form of usable fuel to all people in the whole world. We have been working on research and development of global carbon dioxide recycling for the use of renewable energy in the form of methane via electrolytic hydrogen generation using carbon dioxide as the feedstock. We created energy-saving cathodes for hydrogen production, anodes for oxygen evolution without chlorine formation in seawater electrolysis, and catalysts for methanation of carbon dioxide and built pilot plants of industrial scale. Recent advances in materials are described. Industrial applications are in progress.
Ekstrapolacja światowego zużycia energii z lat 1990-2010 wskazuje, że całkowite wyczerpanie światowych zasobów ropy naftowej nastąpi w 2040 roku, gazu ziemnego w 2043 roku, uranu w 2046 roku a węgla w 2053 roku. Dla przetrwania ludzkości na całym świecie energia elektryczna powinna być generowana z odnawialnego zródła w formie paliwa dostępnego dla kazdego. Opracowano technologie globalnego recyklingu dwutlenku wegla i zastosowania metanu jako formy odnawialnej energii generowanej poprzez uwodornienie CO2 wodorem produkowanym podczas elektrolizy wody morskiej. Opracowano energooszczedne katody do produkcji wodoru, anody do produkcji tlenu bez towarzyszącej temu emisji gazowego chloru podczas elektrolizy wody morskiej oraz katalizatory stosowane w procesie uwodornienia dwutlenku węgla. Wybudowano również pilotażowa instalacje w skali przemysłowej. Praca opisuje ostatnie postępy w industrializacji procesu.
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photoreduction of carbon dioxide with hydrogen using temperature programmed method
Autorzy:
Kocemba, I.
Nadajczyk, J.
Góralski, J.
Szynkowska, M. I.
Tematy:
usuwanie CO2
fotokatalizy
fotokatalityczna redukcja CO2
metanizacja
removal of CO2
photocatalysis
photocatalytic reduction of CO2
methanation
Pokaż więcej
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Powiązania:
https://bibliotekanauki.pl/articles/779334.pdf  Link otwiera się w nowym oknie
Opis:
The photocatalytic reduction of carbon dioxide with hydrogen was studied by Temperature-Programmed Surface Reaction (TPSR). This process was carried out in a flow reactor that was especially designed and constructed for this purpose. Titanium dioxide (TiO2, Degussa P-25) was used as supports for platinum, ruthenium and nickel catalysts. The experimental results indicated that the activity of photoreduction of CO2 changes as follows: Ru/TiO2> Ni/TiO2>= Pt/TiO2> TiO2.
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-8 z 8

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