Temat: perovskite - Prolib Integro

Skocz do pozycji: 1.

Tytuł:: State of the art and prospects for halide perovskite nanocrystals
Autorzy:: Bladt, Eva
Mora-Seró, Iván
Hofkens, Johan
Dutta, Anirban
Yan, Fei
Pradhan, Narayan
Li, Xiaoming
Scheblykin, Ivan G.
Roeffaers, Maarten B. J.
Rogach, Andrey L.
Hoye, Robert L. Z.
Wang, Yue
Gerhard, Marina
Korgel, Brian A.
Kumar, Sudhir
Zhang, Jin Z.
Samanta, Anunay
Galian, Raquel E.
Kovalenko, Maksym V.
Quan, Li Na
Debroye, Elke
Steele, Julian A.
Bakr, Osman M.
Yang, Peidong
Scheel, Manuel A.
Dey, Amrita
Manna, Liberato
Zhang, Yangning
Tisdale, William A.
Zhang, Qiao
Stolarczyk, Jacek
Cao, Muhan
Vincon, Ilka
Bao, Qiaoliang
Polavarapu, Lakshminarayana
Stranks, Samuel D.
Bodnarchuk, Maryna I.
Biju, Vasudevanpillai
Han, Chuang
Gao, Mengyu
Nag, Angshuman
Sun, Handong
Bals, Sara
Müller-Buschbaum, Peter
Yan, Yong
Shih, Chih-Jen
Demir, Hilmi Volkan
Zhong, Haizheng
Wu, Xian-gang
Mohammed, Omar F.
Son, Dong Hee
Gamelin, Daniel R.
Ha, Seung Kyun
Zeng, Haibo
De, Apurba
Kamat, Prashant V.
Wang, Ziyu
Yin, Jun
Luther, Joseph M.
Ye, Junzhi
Xu, Ke
Pérez-Prieto, Julia
Debnath, Tushar
Chouhan, Lata
Li, Yanxiu
Shamsi, Javad
Krahne, Roman
Feldmann, Jochen
Kshirsagar, Anuraj S.
Li, Liang
Opis:: Metal-halide perovskites have rapidly emerged as one of the most promising materials of the 21st century, with many exciting properties and great potential for a broad range of applications, from photovoltaics to optoelectronics and photocatalysis. The ease with which metal-halide perovskites can be synthesized in the form of brightly luminescent colloidal nanocrystals, as well as their tunable and intriguing optical and electronic properties, has attracted researchers from different disciplines of science and technology. In the last few years, there has been a significant progress in the shape-controlled synthesis of perovskite nanocrystals and understanding of their properties and applications. In this comprehensive review, researchers having expertise in different fields (chemistry, physics, and device engineering) of metal-halide perovskite nanocrystals have joined together to provide a state of the art overview and future prospects of metal-halide perovskite nanocrystal research.
Dostawca treści:: Repozytorium Uniwersytetu Jagiellońskiego

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Skocz do pozycji: 2.

Tytuł:: Molecular Engineering of Azahomofullerene-based Electron Transporting Materials for Efficient and Stable Perovskite Solar Cells
Autorzy:: Kruszyńska, Joanna
Bończak, Bartłomiej
Mahapatra, Apurba
Nikiforow, Kostiantyn
Paczesny, Jan
Yadav, Pankaj
Unal, Muhittin
Nawrocki, Jan
Sadegh, Faranak
Chavan, Rohit D.
Prochowicz, Daniel
Akin, Seckin
Ans, Muhammad
Wydawca:: ACS Publications
Cytata wydawnicza:: Chem. Mater. 2023, 35, 8309−8320. https://doi.org/10.1021/acs.chemmater.3c01995
Opis:: The rational molecular design of fullerene-based molecules with exceptional physical and electrical properties is in high demand to ensure efficient charge transport at the perovskite/electron transport layer interface. In this work, novel azahomofullerene (AHF) is designed, synthesized, and introduced as the interlayer between the SnO2/perovskite interface in planar n−i−p heterojunction perovskite solar cells (PSCs). The AHF molecule (denoted as AHF-4) is proven to enhance charge transfer capability compared to the commonly used fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) due to its superior coordination interaction and electronic coupling with the SnO2 surface. In addition, the AHF-4 interlayer concurrently improves the quality of the perovskite film and reduces charge recombination in PSCs. The resultant AHF-4-based device exhibits a maximum efficiency of 21.43% with lower hysteresis compared to the PCBM device (18.56%). Benefiting from the enhanced stability of the AHF-4 film toward light soaking and elevated temperature, the AHF-4-based devices show improved stability under continuous 1 sun illumination at the maximum power point and 45 °C. Our work opens a new direction to the design of AHF derivatives with favorable physical and electrical properties as an interlayer material to improve both the performance and stability of PSCs.
National Science Centre
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 3.

Tytuł:: Revealing the Impact of Aging on Perovskite Solar Cells Employing Nickel Phthalocyanine-Based Hole Transporting Material
Autorzy:: Kruszyńska, Joanna
Fazlı, Hilal
Mahapatra, Apurba
Nikiforow, Kostiantyn
Unal, Muhittin
Yadav, Pankaj
Güzel, Emre
Biyiklioglu, Zekeriya
Chavan, Rohit D.
Prochowicz, Daniel
Akin, Seckin
Ans, Muhammad
Wydawca:: Wiley
Cytata wydawnicza:: M. Ans, Z. Biyiklioglu, A. Mahapatra, R. D. Chavan, J. Kruszyńska, M. Unal, H. Fazlı, K. Nikiforow, P. Yadav, S. Akin, E. Güzel, D. Prochowicz, Revealing the Impact of Aging on Perovskite Solar Cells Employing Nickel Phthalocyanine-Based Hole Transporting Material. Adv. Sci. 2024, 11, 2405284. https://doi.org/10.1002/advs.202405284
Opis:: National Science Centre (grant SONATA BIS 10, no. 2020/38/E/ST5/00267) and the Scientific Research Projects Coordination Unit of Sakarya University of Applied Sciences (Project Number: 212–2024).
The enhancement of the photovoltaic performance upon the aging process at particular environment is often observed in perovskite solar cells (PSCs), particularly for the devices with 2,2′,7,7′-tetrakis(N,N-di(4-methoxyphenyl) amino)−9,9′-spirobifluorene (spiro-OMeTAD) as hole transporting material (HTM). In this work, for the first time the effect of aging the typical n-i-p PSCs employing nickel phthalocyanine (coded as Bis-PF-Ni) solely as dopant-free HTM is investigated and as an additive in spiro-OMeTAD solution. This study reveals that the prolong aging of these devices at dry air condition (RH = 2%, 25 °C) is beneficial for the improvement of their performances. Various bulk and surface characterization techniques are utilized to understand the factors behind the spontaneous efficiency enhancement of the devices after storage. As a result, the changes in properties of the Bis-PF-Ni layer are observed and at perovskite/Bis-PF-Ni interface, which ultimately improves the charge transport and reduces non-radiative recombination. In addition, the devices with Bis-PF-Ni HTM reveal enhanced long-term ambient and thermal stability compared to the PSCs based on doped spiro-OMeTAD.
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 4.

Tytuł:: Dual Interface Modification for Reduced Nonradiative Recombination in n–i–p Methylammonium-Free Perovskite Solar Cells
Autorzy:: M. Barea, Eva
Rodriguez-Pereira, Jhonatan
Zarazua, Isaac
Contreras-Solorio, David Armando
Pascual, Jorge
Turren-Cruz, Silver-Hamill
Esparza, Diego
Akin, Seckin
Mora-Seró, Iván
Prochowicz, Daniel
Rodriguez-Perez, Juan José
Martinez-Pastor, Juan P.
Ans, Muhammad
Diaz Perez, Teresa
Wydawca:: American Chemical Society
Cytata wydawnicza:: ACS Appl. Mater. Interfaces 2025, 17, 8610−8618. https://doi.org/10.1021/acsami.4c20462
Opis:: High defect concentrations at the interfaces are the basis of charge extraction losses and instability in perovskite solar cells. Surface engineering with organic cations is a common practice to solve this issue. However, the full implications of the counteranions of these cations for device functioning are often neglected. In this work, we used 4-fluorophenethylammonium cation with varying halide counteranions for the modification of both interfaces in methylammonium-free Pb-based n–i–p devices, observing significant differences among iodide, bromide, and chloride. The cation treatment of the buried and top interfaces resulted in improved surface quality of the perovskite films and largely improved carrier dynamics with reduced nonradiative recombination. Consequently, the optimal interface-modified methylammonium-free perovskite solar cells surpassed 20% efficiency and demonstrated remarkable operational stability. Our findings underscore the potential of comprehensive surface engineering strategies in advancing the perovskite film and device quality, thereby facilitating their broader and more successful applications.
S.H.T.-C. gratefully acknowledges funding from the Ministry of Science and Innovation of Spain under Ayudas Ramón y Cajal (RYC2022-035578-I) and POLONEZ BIS Project No. 2021/43/P/ST5/01780 cofunded by the National Science Centre and the EU’s H2020 research and innovation programme under the MSCA 945339 for the financial support during this work. J.J.R.-P. acknowledges the CONAHCyT Mexico for PHD scholarship. J.P. acknowledges support from Energy for future – E4F Postdoctoral fellowship program H2020-MSCA-COFUND-2020 (101034297). J.R.-P. acknowledge the Ministry of Education, Youth and Sports of the Czech Republic for supporting CEMNAT (LM2023037) infrastructure for providing XPS access. E.M.B. acknowledges project EPCESBI–UJI-B2022-08. This work was partially supported by the project “Step-Up” TED2021-131600B-C31, funded by the Ministerio de Ciencia e Innovación MCIN/AEI/10.13039/501100011033 and the European Union “NextGeneration EU/PRTR.”
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 5.

Tytuł:: Effect of 1,3-Disubstituted Urea Derivatives as Additives on the Efficiency and Stability of Perovskite Solar Cells
Autorzy:: Gupta, Sanjeev K.
Kruszyńska, Joanna
Akman, Erdi
Yadav, Pankaj
Gajjar, Pankaj N.
Prochowicz, Daniel
Akin, Seckin
Patel, Manushi J.
Sadegh, Faranak
Tavakoli, Mohammad Mahdi
Wydawca:: ACS Publications
Cytata wydawnicza:: ACS Appl. Energy Mater. 2022, 5, 13617–13626. https://doi.org/10.1021/acsaem.2c02313
Opis:: National Science Centre
Additive engineering in perovskites precursor solution is one of the most effective methods to fabricate high-quality perovskite films. Finding proper additives for morphology improvement and passivation of the perovskite defects is critical to fabricate highly efficient and stable perovskite solar cells (PSCs). In this work, 1,3-disubstituted urea additives are employed to study the effect of different substituents at -NH moiety on the quality of the perovskite layer and device performance. By adding 1,3-diphenyl urea (Ph-urea) or 1,3-di(tert-butyl)urea (tBu-urea) into the precursors, the crystallization process leads to the formation of perovskite films with larger grains and lower defect densities as compared to the non-substituted urea additive. Using density functional theory (DFT) calculations and experimental spectroscopic measurements, we found that the selected 1,3-disubstituted ureas are prone to form stronger coordination interaction with undercoordinated Pb2+ ions than the urea. Applying this additive engineering to the devices reduced the current density–voltage (J–V) hysteresis and improved the photovoltaic performance, resulting in maximum power conversion efficiencies of 21.7% and 21.2% for the Ph-urea and tBu-urea modified devices, respectively. In addition, the device with Ph-urea enhanced long-term stability, where it remains 90% of its initial efficiency, while the device with tBu-urea degrades fast reaching 20% of its initial efficiency after aging for 90 days due to the high moisture permeability of tBu-urea.
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 6.

Tytuł:: Elucidation of the role of guanidinium incorporation in single-crystalline MAPbI3 perovskite on ion migration and activation energy
Autorzy:: Kumar, Pawan
Trivedi, Suverna
Mahapatra, Apurba
Yadav, Pankaj
Kalam, Abul
Lewiński, Janusz
Nawrocki, Jan
Prochowicz, Daniel
Runjhun, Rashmi
Tavakoli, Mohammad Mahdi
Wydawca:: Royal Society of Chemistry
Cytata wydawnicza:: Phys. Chem. Chem. Phys., 2020,22, 11467-11473. https://doi.org/10.1039/D0CP01119C
Opis:: Ion migration plays a significant role in the overall stability and power conversion efficiency of perovskite solar cells (PSCs). This process was found to be influenced by the compositional engineering of the A-site cation in the perovskite crystal structure. However, the effect of partial A-site cation substitution in a methylammonium lead iodide (MAPbI3) perovskite on the ion migration process and its activation energy is not fully understood. Here we study the effect of a guanidinium (GUA) cation on the ion transport dynamics in the single crystalline GUAxMA1−xPbI3 perovskite composition using temperature-dependent electrochemical impedance spectroscopy (EIS). We find that the small substitution of MA with GUA decreases the activation energy for iodide ion migration in comparison to pristine MAPbI3. The presence of a large GUA cation in the 3D perovskite structure induces lattice enlargement, which perturbs the atomic interactions within the perovskite lattice. Consequently, the GUAxMA1−xPbI3 crystal exhibits a higher degree of hysteresis during current–voltage (J–V) measurements than the single-crystalline MAPbI3 counterpart. Our results provide the fundamental understanding of hysteresis, which is commonly observed in GUA-based PSCs and a general protocol for in-depth electrical characterization of perovskite single crystals.
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 7.

Tytuł:: Enhancing Stability of Microwave-Synthesized Cs2SnxTi1-xBr6 Perovskite by Cation Mixing
Autorzy:: Reyes-Francis, Emmanuel
López-Luke, Tzarara
Julián‐López, Beatriz
Espino-Valencia, Jaime
Rodríguez‐Pereira, Jhonatan
Mora‐Seró, Iván
Esparza, Diego
Prochowicz, Daniel
Echeverría‐Arrondo, Carlos
Turren‐Cruz, Silver‐Hamill
Wydawca:: Wiley-VCH GmbH
Cytata wydawnicza:: ChemSusChem 2025, 18, e202402073. https://doi.org/10.1002/cssc.202402073
Opis:: Conselleria d'Educació, Investigació, Cultura i Esport. Grant Number: CIPROM/2021/078 Narodowe Centrum Nauki. Grant Number: 2021/43/P/ST5/01780 H2020 Marie Skłodowska-Curie Actions. Grant Number: 945339
The double-perovskite material Cs2TiBr6 shows excellent photovoltaic potential, making it a promising alternative to lead-based materials. However, its high susceptibility to degradation in air has raised concerns about its practical application. This study introduces an interesting synthesis approach that significantly enhances the stability of Cs2TiBr6 powder. We implemented a gradual cation exchange process by substituting Ti4+ with Sn4+ in the efficient microwave-assisted synthesis method, developing a double perovskite Cs2SnxTi1-xBr6 type. A systematic study of increasing concentration of Sn4+ in Cs2TiBr6 perovskite has been performed to analyze the effect of Sn-doping degree on the chemical and thermal stability of the material and the optical features in both nitrogen and ambient atmospheres, significantly increasing the stability of the material in the air for over a week. Furthermore, introducing Sn4+ results in a more uniform polygonal crystal morphology of the powders and a slight band gap broadening. We show that microwave-assisted synthesis is highly efficient and cost-effective in producing more sustainable lead-free perovskite materials with enhanced stability and desirable electrical characteristics. This work suggests a promising method for synthesizing perovskite materials, opening new routes for scientific research and applications.
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 8.

Tytuł:: Activity of perovskite catalysts contain Pt or Pd in toluene oxidation
Autorzy:: Borzęcka, A.
Tematy:: VOCs oxidation
perovskite
platinum
palladium; Pokaż więcej
Wydawca:: Fundacja na Rzecz Młodych Naukowców
Powiązania:: https://bibliotekanauki.pl/articles/115915.pdf Link otwiera się w nowym oknie
Opis:: Perovskite catalysts with active phase composed of LaMnO₃ or La_0.75Ag_0.25MnO₃ doped with noble metals — platinum or palladium — were tested for activity in oxidation of toluene. Their impregnation with solution of Pt or Pd compounds increased the catalytic activity. LaMnO₃ with Pt content displayed the highest activity. LaMnO₃ perovskite doped with both noble metals show higher activity than when noble metals were added to La_0.75Ag_0.25MnO₃ perovskite.
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 9.

Tytuł:: High coordination-solvent bathing for efficient crystallization of MA-free triple halide perovskite solar cells
Autorzy:: Kedia, Mayank
Zhuravlova, Anna
Samorì, Paolo
Svetlosanova, Sofya
Saliba, Michael
Zuo, Weiwei
Boehringer, Stephan
Jeronimo-Rendon, Jose J
Zohdi, Mohammadreza
Topcu, Seyma
Roy, Rajarshi
Gholipour, Somayeh
Gaetano Ricciardulli, Antonio
Malekshahi Byranvand, Mahdi
Ataei, Mojtaba
Turren-Cruz, Silver-Hamill
Wydawca:: Royal Society of Chemistry
Cytata wydawnicza:: EES Sol., 2025,1, 30-40 // https://doi.org/10.1039/D4EL00018H
Opis:: Many high-performance perovskite solar cells (PSCs) rely heavily on halogenated antisolvent methods, hampering their potential commercialization. In this work, the industry-compatible dimethyl sulfide (DMS) solvent, which coordinates strongly with the metal cation, is used in a bathing approach to investigate the crystallization of triple halide perovskites. The resulting thin films are more uniform exhibiting preferential crystal growth in the (001) direction (perpendicular to the substrate) and large grains of 444 ± 122 nm compared to 421 ± 147 nm for the reference films. Moreover, the electron diffusion length and lifetimes are enhanced from 1 to 3 μm and from 551 to 1050 ns, respectively, compared to the reference film. The champion solar cell based on our approach exhibits a power conversion efficiency (PCE) of 20.6%, comparable to the conventional lab-scale counterpart at 21.4%. Additionally, the long-term stability of our devices shows that 88% (similar to the reference at 93%) of the initial performance is retained after 60 days at room temperature with 60% relative humidity.
S.-H. T.-C. gratefully acknowledges funding from the Ministry of Science and Innovation of Spain under Ayudas Ramón y Cajal (RYC2022-035578-I) and the POLONEZ Bis project No. 2021/43/P/ST5/01780 co-funded by the National Science Centre and the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement no. 945339 for the financial support during this work. A. G. R. and P. S. acknowledge Agence Nationale de la Recherche through the Interdisciplinary Thematic Institute SysChem via the IdEx Unistra (ANR-10-IDEX-0002) within the program Investissement d’Avenir, the Foundation Jean-Marie Lehn and the Institut Universitaire de France (IUF). M. S. thanks the German Research Foundation (DFG) for funding (SPP2196, 431314977/GRK 2642). M. S., and M. M. B. thank Helmholtz Young Investigator Group FRONTRUNNER. M. S. acknowledges funding from the European Research Council under the Horizon Europe programme (LOCAL-HEAT, grant agreement no. 101041809). The views and opinions expressed are solely those of the authors and do not necessarily reflect those of the European Union or the European Research Council. Neither the European Union nor the granting authority can be held responsible for them. M. S. acknowledges funding from the German Bundesministerium für Bildung and Forschung (BMBF), project “NETPEC” (01LS2103E).
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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Skocz do pozycji: 10.

Tytuł:: Improvement of Light Output of MAPbBr3 Single Crystal for Ultrafast and Bright Cryogenic Scintillator
Autorzy:: Braueninger-Wemer, Philipp
Birowosuto, Muhammad Danang
Kowal, Dominik
Ray, Samit Kumar
Kuddus Sheikh, Md Abdul
Mahato, Somnath
Makowski, Michal
Drozdowski, Winicjusz
Witkowski, Marcin E.
Shaona, Bose
Wydawca:: ACS Publications
Cytata wydawnicza:: J. Phys. Chem. Lett. 2024, 15, 14, 3713–3720. https://doi.org/10.1021/acs.jpclett.4c00379
Opis:: Polish National Science Centre (POLONEZ BIS 2) under Agreement UMO-2022/45/P/ST3/04170.
The remarkable brightness and rapid scintillation observed in perovskite single crystals (SCs) become even more striking when they are operated at cryogenic temperatures. In this study, we present advancements in enhancing the scintillation properties of methylammonium lead bromide (MAPbBr3) SCs by optimizing the synthesis process. We successfully synthesized millimeter-sized MAPbBr3 SCs with bright green luminescence under UV light. However, both MAPbBr3 (Control-1M and THF-0.4M) SCs display notable radioluminescence exclusively at low temperatures due to their phase transitions. Notably, the THF-0.4M SCs exhibit a remarkable improvement in radioluminescence light yield, surpassing Control-1M SCs more than 2-fold. Further, THF-0.4M SCs demonstrate an ultrafast decay component of 0.52 ns (82.2%) and a slower component of 1.80 ns (17.8%), contributing to a rapid scintillation response at low temperatures. Therefore, the amalgamation of ultrafast decay components and improved radioluminescence light yield equips THF-0.4M SCs to emerge as a top choice for perovskite scintillators for X-ray timing applications.
Dostawca treści:: Repozytorium Centrum Otwartej Nauki

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